DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ma, Rory | ko |
dc.contributor.author | Hong, Kiryong | ko |
dc.contributor.author | Kim, Yujin | ko |
dc.contributor.author | Lee, Jae Hyuk | ko |
dc.contributor.author | Kim, Tae Kyu | ko |
dc.date.accessioned | 2024-07-05T07:00:11Z | - |
dc.date.available | 2024-07-05T07:00:11Z | - |
dc.date.created | 2024-02-28 | - |
dc.date.issued | 2021-10 | - |
dc.identifier.citation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.42, no.10, pp.1379 - 1382 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | http://hdl.handle.net/10203/320160 | - |
dc.description.abstract | Ru L-3-edge time-resolved X-ray absorption spectroscopy (TR-XAS) was applied to unravel photo-induced excited state dynamics of solvated [Ru(m-bpy)(3)](2+) (m-bpy = 6-methyl-2,2 '-bipyridine) complex. The Ru L-3-edge probes 2p core-level transitions, enabling to monitor the electronic structure of excited (3)dd state. TR-XAS and time-dependent density functional theory were utilized to directly visualize the charge density of (3)dd state around the Ru atom during the relaxation cascade of [Ru(m-bpy)(3)](2+) complex. The formation of (3)dd state is attributed to the reduced effective ligand field strength, which was derived from the TR-XAS of (3)dd state at 100 ps. These results highlight the role of ligand-field (3)dd state in the photo-induced relaxation dynamics of [Ru(m-bpy)(3)](2+) complex. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Time-resolved X-Ray Absorption Spectroscopy of Solvated [Ru(m-bpy)3]2+ Complex: Electronic Structures of 3dd State | - |
dc.type | Article | - |
dc.identifier.wosid | 000682355700001 | - |
dc.identifier.scopusid | 2-s2.0-85112591709 | - |
dc.type.rims | ART | - |
dc.citation.volume | 42 | - |
dc.citation.issue | 10 | - |
dc.citation.beginningpage | 1379 | - |
dc.citation.endingpage | 1382 | - |
dc.citation.publicationname | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1002/bkcs.12377 | - |
dc.identifier.kciid | ART002767739 | - |
dc.contributor.localauthor | Kim, Tae Kyu | - |
dc.contributor.nonIdAuthor | Ma, Rory | - |
dc.contributor.nonIdAuthor | Hong, Kiryong | - |
dc.contributor.nonIdAuthor | Kim, Yujin | - |
dc.contributor.nonIdAuthor | Lee, Jae Hyuk | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | X-ray absorption | - |
dc.subject.keywordAuthor | Time-dependent density functional theory | - |
dc.subject.keywordAuthor | Time-resolved X-ray spectroscopy | - |
dc.subject.keywordAuthor | Synchrotron | - |
dc.subject.keywordAuthor | Ru(II) complexes | - |
dc.subject.keywordPlus | SPIN-CROSSOVER | - |
dc.subject.keywordPlus | BASIS-SETS | - |
dc.subject.keywordPlus | LIGAND | - |
dc.subject.keywordPlus | LOCALIZATION | - |
dc.subject.keywordPlus | VALENCE | - |
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