DC Field | Value | Language |
---|---|---|
dc.contributor.author | Wang, Jinming | ko |
dc.contributor.author | Kim, Eunhyo | ko |
dc.contributor.author | Kumar, Dharani Praveen | ko |
dc.contributor.author | Rangappa, Akkammagari Putta | ko |
dc.contributor.author | Kim, Yujin | ko |
dc.contributor.author | Zhang, Yuexing | ko |
dc.contributor.author | Kim, Tae Kyu | ko |
dc.date.accessioned | 2024-06-24T07:00:29Z | - |
dc.date.available | 2024-06-24T07:00:29Z | - |
dc.date.created | 2024-02-28 | - |
dc.date.issued | 2022-02 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.61, no.6 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/319990 | - |
dc.description.abstract | Dual-atom-site catalysts (DACs) have emerged as a new frontier in heterogeneous catalysis because the synergistic effect between adjacent metal atoms can promote their catalytic activity while maintaining the advantages of single-atom-site catalysts, such as almost 100 % atomic efficiency and excellent hydrocarbon selectivity. In this study, cobalt-based atom site catalysts with a Co-2-N coordination structure were synthesized and used for photodriven CO2 reduction. The resulting CoDAC containing 3.5 % Co atoms demonstrated a superior atom ratio for CO2 reduction catalytic performance, with 65.0 % CH4 selectivity, which far exceeds that of cobalt-based single-atom-site catalysts (CoSACs). The intrinsic reason for the superior activity of CoDACs is the excellent adsorption strength of CO2 and CO* intermediates at dimeric Co active sites. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Highly Durable and Fully Dispersed Cobalt Diatomic Site Catalysts for CO2 Photoreduction to CH4 | - |
dc.type | Article | - |
dc.identifier.wosid | 000734677200001 | - |
dc.identifier.scopusid | 2-s2.0-85121684995 | - |
dc.type.rims | ART | - |
dc.citation.volume | 61 | - |
dc.citation.issue | 6 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.202113044 | - |
dc.contributor.localauthor | Kim, Tae Kyu | - |
dc.contributor.nonIdAuthor | Wang, Jinming | - |
dc.contributor.nonIdAuthor | Kim, Eunhyo | - |
dc.contributor.nonIdAuthor | Kumar, Dharani Praveen | - |
dc.contributor.nonIdAuthor | Rangappa, Akkammagari Putta | - |
dc.contributor.nonIdAuthor | Kim, Yujin | - |
dc.contributor.nonIdAuthor | Zhang, Yuexing | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | CH4 formation | - |
dc.subject.keywordAuthor | CO2 photoreduction | - |
dc.subject.keywordAuthor | dual-atom active sites | - |
dc.subject.keywordAuthor | heterogeneous catalysis | - |
dc.subject.keywordAuthor | photocatalysis | - |
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