DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Kang, Sung-Ho | - |
dc.contributor.advisor | 강성호 | - |
dc.contributor.author | Lee, Yun-Mi | - |
dc.contributor.author | 이윤미 | - |
dc.date.accessioned | 2011-12-13T04:49:09Z | - |
dc.date.available | 2011-12-13T04:49:09Z | - |
dc.date.issued | 2003 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=180059&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/31948 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 2003.2, [ ii, 83 p. ] | - |
dc.description.abstract | For the synthesis of dysiherbaine 1, the bicyclic oxazolidinone 40 has been synthesized starting from mannitol. cis,cis-Diene 131 could be accessed via palladium-catalyzed cross-coupling reaction of vinyl iodide 106 and terminal acetylene 90 under Sonogashira conditions. 131 was cyclized stereoselectively by intramolecular mercuriocyclization to give cis-dihydropyran 138b. N-Methyl- oxazolidinone 130 was achieved via iodocyclization of imidates. 130 was cyclized by an intramolecular $S_N2$ reaction regiospecifically to give the desired tetrahydrofuran rather than tetrahydropyran. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.subject | dysiherbaine | - |
dc.subject | 디시허베인 | - |
dc.title | Synthetic studies on dysiherbaine | - |
dc.title.alternative | 디시허베인의 합성에 관한 연구 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 180059/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 020013459 | - |
dc.contributor.localauthor | Kang, Sung-Ho | - |
dc.contributor.localauthor | 강성호 | - |
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