DC Field | Value | Language |
---|---|---|
dc.contributor.author | Manna, Madhu Sudan | ko |
dc.contributor.author | Yoo, Seok Yeol | ko |
dc.contributor.author | Sharique, Mohammed | ko |
dc.contributor.author | Choi, Hyoju | ko |
dc.contributor.author | Pudasaini, Bimal | ko |
dc.contributor.author | Baik, Mu-Hyun | ko |
dc.contributor.author | Tambar, Uttam K. | ko |
dc.date.accessioned | 2023-09-19T09:03:01Z | - |
dc.date.available | 2023-09-19T09:03:01Z | - |
dc.date.created | 2023-09-19 | - |
dc.date.created | 2023-09-19 | - |
dc.date.created | 2023-09-19 | - |
dc.date.issued | 2023-08 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.62, no.35 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/312758 | - |
dc.description.abstract | We report a copper-catalyzed, regioselective, and stereospecific alkylation of unbiased internal allylic carbonates with functionalized alkyl and aryl Grignard reagents. The reactions exhibit high stereospecificity and regioselectivity for either S(N)2 or S(N)2 ' products under two sets of copper-catalyzed conditions, which enables the preparation of a broad range of products with E-alkene selectivity. Density functional theory calculations reveal the origins of the regioselectivity based on the different behaviors of homo- and heterocuprates. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Copper-Catalyzed Regiodivergent Internal Allylic Alkylations | - |
dc.type | Article | - |
dc.identifier.wosid | 001053110800017 | - |
dc.identifier.scopusid | 2-s2.0-85164945554 | - |
dc.type.rims | ART | - |
dc.citation.volume | 62 | - |
dc.citation.issue | 35 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.202304848 | - |
dc.contributor.localauthor | Baik, Mu-Hyun | - |
dc.contributor.nonIdAuthor | Manna, Madhu Sudan | - |
dc.contributor.nonIdAuthor | Sharique, Mohammed | - |
dc.contributor.nonIdAuthor | Pudasaini, Bimal | - |
dc.contributor.nonIdAuthor | Tambar, Uttam K. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Allylic Alkylation | - |
dc.subject.keywordAuthor | Copper | - |
dc.subject.keywordAuthor | Density Functional Calculations | - |
dc.subject.keywordAuthor | Regioselecitvity | - |
dc.subject.keywordAuthor | Stereospecific | - |
dc.subject.keywordPlus | CONJUGATE ADDITION | - |
dc.subject.keywordPlus | PHOSPHOROTHIOATE ESTERS | - |
dc.subject.keywordPlus | ORGANOCUPRATE CLUSTERS | - |
dc.subject.keywordPlus | GRIGNARD-REAGENTS | - |
dc.subject.keywordPlus | ENERGIES | - |
dc.subject.keywordPlus | REACTIVITIES | - |
dc.subject.keywordPlus | SUBSTITUTION | - |
dc.subject.keywordPlus | CARBONATES | - |
dc.subject.keywordPlus | MECHANISM | - |
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