DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ahmad, Waleed | ko |
dc.contributor.author | Jeong, Hochan | ko |
dc.contributor.author | Nahm, Ho Hyun | ko |
dc.contributor.author | Lee, Yeunhee | ko |
dc.contributor.author | Park, Eunseuk | ko |
dc.contributor.author | Lee, Heehyeon | ko |
dc.contributor.author | Ali, Ghulam | ko |
dc.contributor.author | Kim, Yong-Hyun | ko |
dc.contributor.author | Jurng, Jongsoo | ko |
dc.contributor.author | Oh, Youngtak | ko |
dc.date.accessioned | 2023-05-22T01:00:15Z | - |
dc.date.available | 2023-05-22T01:00:15Z | - |
dc.date.created | 2023-05-19 | - |
dc.date.created | 2023-05-19 | - |
dc.date.created | 2023-05-19 | - |
dc.date.issued | 2023-07 | - |
dc.identifier.citation | CHEMICAL ENGINEERING JOURNAL, v.467 | - |
dc.identifier.issn | 1385-8947 | - |
dc.identifier.uri | http://hdl.handle.net/10203/306881 | - |
dc.description.abstract | Thermal catalytic oxidation at room temperature using a noble metal catalyst is a rapid, stable, and efficient removal strategy for HCHO, a ubiquitous indoor air pollutant. However, the catalytic oxidation optimization through the support defect control has been barely explored. We prepared an oxygen vacancy-rich anatase TiO2 (VO-TiO2) as electron transfer catalyst support for the efficient catalytic conversion of HCHO to CO2 and H2O. VO-TiO2, prepared by chemical vapor condensation with post heat treatment, exhibits void-embedded nanostructures and electron paramagnetic activity, which governs the deposition pattern of Pt nanoparticles upon the impregnation. Pt/VO-TiO2 (0.086 wt% Pt) converted 100% of 10 ppm HCHO at room temperature and 200,000 cm3 h−1 gcat−1 GHSV in >250 min. The X-ray absorption (XAS) studies of used catalysts confirmed the conservation of metallic state of Pt only in oxygen vacancy-rich anatase TiO2 (VO-TiO2). The First-principles density-functional theory calculations revealed that the excess electrons at the oxygen vacancies in VO-TiO2 stabilize the otherwise-vulnerable Pt nanoparticles. This study demonstrates an effective defect control strategy for transforming a TiO2 support into a dynamic electron transfer catalyst platform. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.title | Metal-anchoring, metal oxidation-resistance, and electron transfer behavior of oxygen vacancy-rich TiO2 in supported noble metal catalyst for room temperature HCHO conversion | - |
dc.type | Article | - |
dc.identifier.wosid | 001006581000001 | - |
dc.identifier.scopusid | 2-s2.0-85159095408 | - |
dc.type.rims | ART | - |
dc.citation.volume | 467 | - |
dc.citation.publicationname | CHEMICAL ENGINEERING JOURNAL | - |
dc.identifier.doi | 10.1016/j.cej.2023.143412 | - |
dc.contributor.localauthor | Nahm, Ho Hyun | - |
dc.contributor.localauthor | Kim, Yong-Hyun | - |
dc.contributor.nonIdAuthor | Ahmad, Waleed | - |
dc.contributor.nonIdAuthor | Park, Eunseuk | - |
dc.contributor.nonIdAuthor | Lee, Heehyeon | - |
dc.contributor.nonIdAuthor | Ali, Ghulam | - |
dc.contributor.nonIdAuthor | Jurng, Jongsoo | - |
dc.contributor.nonIdAuthor | Oh, Youngtak | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Oxygen vacancy -rich TiO 2 | - |
dc.subject.keywordAuthor | Pt nanoparticles | - |
dc.subject.keywordAuthor | Electronic metal -support interaction | - |
dc.subject.keywordAuthor | Electron transfer catalyst | - |
dc.subject.keywordAuthor | Room -temperature catalytic HCHO conversion | - |
dc.subject.keywordPlus | FORMALDEHYDE OXIDATION | - |
dc.subject.keywordPlus | PT/TIO2 CATALYSTS | - |
dc.subject.keywordPlus | TITANIUM-DIOXIDE | - |
dc.subject.keywordPlus | GASEOUS FORMALDEHYDE | - |
dc.subject.keywordPlus | REDUCED TIO2 | - |
dc.subject.keywordPlus | BLACK TIO2 | - |
dc.subject.keywordPlus | SURFACE | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | ANATASE | - |
dc.subject.keywordPlus | PLATINUM | - |
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