Deconstructive Pyridylation of Unstrained Cyclic Amines through a One-Pot Umpolung Approach

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A one-pot umpolung method for the ring-opening pyridylation of unstrained cyclic amines was developed using N-amidopyridinium salts. This process involves the formation of electron donor-acceptor complexes between bromide and N-amidopyridinium salts, ultimately leading to the functionalization of pyridines. This protocol is compatible with a range of 5-or 6-membered cyclic amines and pyridines, thereby providing a powerful synthon for preparing C4functionalized pyridines under visible-light conditions in the absence of an external photocatalyst.
Publisher
AMER CHEMICAL SOC
Issue Date
2023-04
Language
English
Article Type
Article
Citation

ORGANIC LETTERS, v.25, no.15, pp.2722 - 2727

ISSN
1523-7060
DOI
10.1021/acs.orglett.3c00922
URI
http://hdl.handle.net/10203/306876
Appears in Collection
CH-Journal Papers(저널논문)
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