Pincer-type ligand having acridane structure and metal complex using the same아크리단 구조를 갖는 집게형 리간드 및 이를 이용한 금속착물

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Disclosed are a pincer-type ligand having a structurally rigid acridane structure and a metal complex consisting of the pincer-type ligand and a metal bound to each other, and exhibiting high reactivity and stability during a variety of bonding activation reactions. T-shaped complexes can be prepared from acriPNP(4,5-bis(diisopropylphosphino)-2,7,9,9-tetramethyl-9H-acridin-10-ide), which is a pincer-type PNP ligand having an acridane structure, and metal complexes, which can be structurally rigid and thus exhibit excellent reactivity and stability based on minimized structural change thereof, can be prepared by introducing an acridane structure into the backbone thereof. The PNP ligand is structurally stable and has novel chemical properties, as compared to conventional similar ligands, and thus can be utilized in a wide range of catalytic reactions and material chemistry.
Assignee
KAIST
Country
US (United States)
Application Date
2021-02-02
Application Number
17165636
Registration Date
2023-03-07
Registration Number
11596934
URI
http://hdl.handle.net/10203/306060
Appears in Collection
CH-Patent(특허)
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