DC Field | Value | Language |
---|---|---|
dc.contributor.author | Choi, Wonjun | ko |
dc.contributor.author | Kim, Minseok | ko |
dc.contributor.author | Lee, Kangjae | ko |
dc.contributor.author | Park, Seongjin | ko |
dc.contributor.author | Hong, Sungwoo | ko |
dc.date.accessioned | 2023-01-03T05:00:09Z | - |
dc.date.available | 2023-01-03T05:00:09Z | - |
dc.date.created | 2023-01-03 | - |
dc.date.created | 2023-01-03 | - |
dc.date.created | 2023-01-03 | - |
dc.date.issued | 2022-12 | - |
dc.identifier.citation | ORGANIC LETTERS, v.24, no.51, pp.9452 - 9457 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/10203/303903 | - |
dc.description.abstract | The photoinduced C4-selective C-H borylation of pyridines was achieved using electron donor-acceptor complexes derived from a Lewis base and N-amidopyridinium salts under external oxidant- and photocatalyst-free conditions. Notably, the nucleophilic character of phosphite-ligated boryl radicals enables addition of a radical to position C4 of pyridinium salts to afford C4-borylated heteroarenes that are otherwise difficult to obtain. This approach provides a versatile platform for the installation of both phosphite- and amine-coordinated boron groups on a series of pyridines under mild conditions, demonstrating excellent C4-positional selectivity for the pyridine scaffolds. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | C4-Selective C–H Borylation of Pyridinium Derivatives Driven by Electron Donor–Acceptor Complexes | - |
dc.type | Article | - |
dc.identifier.wosid | 000901584800001 | - |
dc.identifier.scopusid | 2-s2.0-85144426594 | - |
dc.type.rims | ART | - |
dc.citation.volume | 24 | - |
dc.citation.issue | 51 | - |
dc.citation.beginningpage | 9452 | - |
dc.citation.endingpage | 9457 | - |
dc.citation.publicationname | ORGANIC LETTERS | - |
dc.identifier.doi | 10.1021/acs.orglett.2c03882 | - |
dc.contributor.localauthor | Hong, Sungwoo | - |
dc.contributor.nonIdAuthor | Choi, Wonjun | - |
dc.contributor.nonIdAuthor | Kim, Minseok | - |
dc.contributor.nonIdAuthor | Lee, Kangjae | - |
dc.contributor.nonIdAuthor | Park, Seongjin | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | LIGHT | - |
dc.subject.keywordPlus | RADICALS | - |
dc.subject.keywordPlus | SCOPE | - |
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