DC Field | Value | Language |
---|---|---|
dc.contributor.author | Senthil, Shuruthi | ko |
dc.contributor.author | Kwon, Seongyeon | ko |
dc.contributor.author | Fehn, Dominik | ko |
dc.contributor.author | Im, Hoyoung | ko |
dc.contributor.author | Gau, Michael R. | ko |
dc.contributor.author | Carroll, Patrick J. | ko |
dc.contributor.author | Baik, Mu-Hyun | ko |
dc.contributor.author | Meyer, Karsten | ko |
dc.contributor.author | Mindiola, Daniel J. | ko |
dc.date.accessioned | 2022-12-26T08:00:10Z | - |
dc.date.available | 2022-12-26T08:00:10Z | - |
dc.date.created | 2022-12-12 | - |
dc.date.created | 2022-12-12 | - |
dc.date.issued | 2022-10 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.61, no.52 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/303708 | - |
dc.description.abstract | Decarbonylation along with P-atom transfer from the phosphaethynolate anion, PCO-, to the Nb-IV complex [(PNP)NbCl2((NBuAr)-Bu-t)] (1) (PNP=N[2-(PPr2)-Pr-i-4-methylphenyl](2)(-); Ar=3,5-Me2C6H3) results in its coupling with one of the phosphine arms of the pincer ligand to produce a phosphanylidene phosphorane complex [(PNPP)NbCl((NBuAr)-Bu-t)] (2). Reduction of 2 with CoCp*(2) cleaves the P-P bond to form the first neutral and terminal phosphido complex of a group 5 transition metal, namely, [(PNP)Nb equivalent to P((NBuAr)-Bu-t)] (3). Theoretical studies have been used to understand both the coupling of the P-atom and the reductive cleavage of the P-P bond. Reaction of 3 with a two-electron oxidant such as ethylene sulfide results in a diamagnetic sulfido complex having a P-P coupled ligand, namely [(PNPP)Nb=S((NBuAr)-Bu-t)] (4). | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Metal-Ligand Cooperativity to Assemble a Neutral and Terminal Niobium Phosphorus Triple Bond (Nb equivalent to P) | - |
dc.type | Article | - |
dc.identifier.wosid | 000889071300001 | - |
dc.identifier.scopusid | 2-s2.0-85143223793 | - |
dc.type.rims | ART | - |
dc.citation.volume | 61 | - |
dc.citation.issue | 52 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.202212488 | - |
dc.contributor.localauthor | Baik, Mu-Hyun | - |
dc.contributor.nonIdAuthor | Senthil, Shuruthi | - |
dc.contributor.nonIdAuthor | Fehn, Dominik | - |
dc.contributor.nonIdAuthor | Im, Hoyoung | - |
dc.contributor.nonIdAuthor | Gau, Michael R. | - |
dc.contributor.nonIdAuthor | Carroll, Patrick J. | - |
dc.contributor.nonIdAuthor | Meyer, Karsten | - |
dc.contributor.nonIdAuthor | Mindiola, Daniel J. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Atom Transfer | - |
dc.subject.keywordAuthor | Niobium | - |
dc.subject.keywordAuthor | Phosphaethynolate | - |
dc.subject.keywordAuthor | Phosphido | - |
dc.subject.keywordAuthor | Phosphorus | - |
dc.subject.keywordPlus | MONOMERIC MOLYBDENUM | - |
dc.subject.keywordPlus | LOW-COORDINATE | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | PHOSPHIDE | - |
dc.subject.keywordPlus | CLEAVAGE | - |
dc.subject.keywordPlus | ELEMENTS | - |
dc.subject.keywordPlus | DECARBONYLATION | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | CONVERSION | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.