DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shin, Taeil | ko |
dc.contributor.author | Jang, Taehoon | ko |
dc.contributor.author | Kim, Hyunwoo | ko |
dc.date.accessioned | 2022-11-30T01:00:42Z | - |
dc.date.available | 2022-11-30T01:00:42Z | - |
dc.date.created | 2022-11-14 | - |
dc.date.created | 2022-11-14 | - |
dc.date.issued | 2022-11 | - |
dc.identifier.citation | ORGANOMETALLICS, v.41, no.21, pp.3032 - 3037 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10203/301321 | - |
dc.description.abstract | Propene (propylene) is the most important hydroformylation reactant on an industrial scale, representing approximately 75% of the global consumption of oxo chemicals. Both n-butanal and isobutanal, the products of propene hydroformylation, are valuable precursors, and thus controlling the regioselectivity in this reaction is of academic and industrial interest. In the Rh-catalyzed propene hydroformylation, regioselective reactions have been achieved by a modifying ligand. Although highly normal selective (n/iso > 50) ligands have been reported, iso-selective (n/iso < 1) ligands are limited and more importantly show a significantly reduced activity (TOF < 1000 h-1). Herein, we report a highly reactive and regio-controlled (n/iso = 1) propene hydroformylation enabled by Rh catalysis with a sterically bulky pi-acceptor phosphorus (bicyclic bridgehead phosphoramidite (briphos)) ligand. In addition, a briphos/PPh3 ligand combination results in a mixed-ligand Rh(I) complex that shows regioselectivity (n/iso = 1) and high reactivity (TOF = 22,700 h-1) and stability during propene hydroformylation. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Synergistic Ligand Effect in Rhodium(I)-Catalyzed Regio-Controlled Propene Hydroformylation | - |
dc.type | Article | - |
dc.identifier.wosid | 000878342800001 | - |
dc.identifier.scopusid | 2-s2.0-85140996512 | - |
dc.type.rims | ART | - |
dc.citation.volume | 41 | - |
dc.citation.issue | 21 | - |
dc.citation.beginningpage | 3032 | - |
dc.citation.endingpage | 3037 | - |
dc.citation.publicationname | ORGANOMETALLICS | - |
dc.identifier.doi | 10.1021/acs.organomet.2c00442 | - |
dc.contributor.localauthor | Kim, Hyunwoo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | BRANCHED-SELECTIVE HYDROFORMYLATION | - |
dc.subject.keywordPlus | RHODIUM-CATALYZED HYDROFORMYLATION | - |
dc.subject.keywordPlus | PHOSPHORAMIDITE BRIPHOS LIGANDS | - |
dc.subject.keywordPlus | HIGH REGIOSELECTIVITY | - |
dc.subject.keywordPlus | PHOSPHINE | - |
dc.subject.keywordPlus | ALCOHOLS | - |
dc.subject.keywordPlus | OLEFINS | - |
dc.subject.keywordPlus | COMPLEX | - |
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