DC Field | Value | Language |
---|---|---|
dc.contributor.author | Huang, Huawei | ko |
dc.contributor.author | Xu, Liangliang | ko |
dc.contributor.author | Woo, Dong Yoon | ko |
dc.contributor.author | Kim, Seongbeen | ko |
dc.contributor.author | Kim, Sung Min | ko |
dc.contributor.author | Kim, Yong Kyeong | ko |
dc.contributor.author | Byeon, Jaeho | ko |
dc.contributor.author | Lee, Jinwoo | ko |
dc.date.accessioned | 2022-10-17T08:00:14Z | - |
dc.date.available | 2022-10-17T08:00:14Z | - |
dc.date.created | 2022-10-17 | - |
dc.date.issued | 2023-01 | - |
dc.identifier.citation | CHEMICAL ENGINEERING JOURNAL, v.451 | - |
dc.identifier.issn | 1385-8947 | - |
dc.identifier.uri | http://hdl.handle.net/10203/298977 | - |
dc.description.abstract | Anion-exchange membrane water electrolyzer is a promising and green technology for hydrogen production. However, the high energy barriers for the water dissociation step for breaking the strong H-O-H covalent bond results in sluggish hydrogen evolution reaction (HER) kinetics at the cathode. Herein, we present a strategy to optimize the morphology and surface properties of WO2.7 by introducing oxygen vacancies and doping with various transition metals. The experimental analysis demonstrates that the developed Co-WO2.7-x and Ni-WO2.7-x with ultrafine nanorods structure provide a larger electrochemical surface area than the other synthesized catalysts. Furthermore, theoretical analysis reveals that Co-WO2.7-x has the lowest energy barrier (0.65 eV) for the water dissociation step, which is much lower than that of WO2.7 (2.61 eV). Consequently, the Co-WO2.7-x delivers a current of 10 mA cm(-2) at a small overpotential of 59 mV for alkaline HER. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.title | Refining the surface properties of WO2.7 by vacancy engineering and transition metals doping for enhanced alkaline hydrogen evolution reaction | - |
dc.type | Article | - |
dc.identifier.wosid | 000862926900002 | - |
dc.identifier.scopusid | 2-s2.0-85137291043 | - |
dc.type.rims | ART | - |
dc.citation.volume | 451 | - |
dc.citation.publicationname | CHEMICAL ENGINEERING JOURNAL | - |
dc.identifier.doi | 10.1016/j.cej.2022.138939 | - |
dc.contributor.localauthor | Lee, Jinwoo | - |
dc.contributor.nonIdAuthor | Xu, Liangliang | - |
dc.contributor.nonIdAuthor | Kim, Sung Min | - |
dc.contributor.nonIdAuthor | Kim, Yong Kyeong | - |
dc.contributor.nonIdAuthor | Byeon, Jaeho | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Tungsten oxide | - |
dc.subject.keywordAuthor | Transition metal | - |
dc.subject.keywordAuthor | Doping | - |
dc.subject.keywordAuthor | Alkaline hydrogen evolution | - |
dc.subject.keywordPlus | W18O49 NANOSTRUCTURES | - |
dc.subject.keywordPlus | CARBON | - |
dc.subject.keywordPlus | NI | - |
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