Alcohol-Incorporating Diels-Alder Dimerization of In Situ Formed ortho-Quinamine via Co-Nitrenoid Insertion

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dc.contributor.authorLee, Jeonghyoko
dc.contributor.authorKang, Borako
dc.contributor.authorKim, Dongwookko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2022-09-20T01:00:34Z-
dc.date.available2022-09-20T01:00:34Z-
dc.date.created2022-08-15-
dc.date.issued2022-08-
dc.identifier.citationORGANIC LETTERS, v.24, no.31, pp.5845 - 5850-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/298640-
dc.description.abstractWe disclose herein a Cp*Co(III)(LX)-catalyzed dearomative Diels-Alder dimerization of 2,6-disubstituted phenyl azidoformates. Upon the postulated cobalt-nitrenoid insertion into the neighboring ortho-carbon, the key intermediate of ortho-quinamine was generated for the subsequent dimeric cycloaddition process. A series of experimental and computational studies suggested that the quinolinol ligand of the cobalt catalyst plays a crucial role in the alcoholic solvent incorporation into the o-quinamine moiety, thereby enabling the Diels- Alder dimerization to furnish the bridged tricyclic bisamidation products.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleAlcohol-Incorporating Diels-Alder Dimerization of In Situ Formed ortho-Quinamine via Co-Nitrenoid Insertion-
dc.typeArticle-
dc.identifier.wosid000836258100001-
dc.identifier.scopusid2-s2.0-85136075056-
dc.type.rimsART-
dc.citation.volume24-
dc.citation.issue31-
dc.citation.beginningpage5845-
dc.citation.endingpage5850-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/acs.orglett.2c02392-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorLee, Jeonghyo-
dc.contributor.nonIdAuthorKang, Bora-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusASYMMETRIC DEAROMATIZATION-
dc.subject.keywordPlusENANTIOSELECTIVE SYNTHESIS-
dc.subject.keywordPlusAMINATION-
dc.subject.keywordPlusSESQUITERPENE-
dc.subject.keywordPlusREARRANGEMENT-
dc.subject.keywordPlus2-NAPHTHOLS-
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CH-Journal Papers(저널논문)
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