(A) study on the effect of hydrothermal treatment on the photocatalytic properties of titania synthesized by sol-gel method타이타니아의 졸젤 합성 중 수열처리에 의한 광촉매적 성질 변화 연구

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dc.contributor.advisorIhm, Son-Ki-
dc.contributor.advisor임선기-
dc.contributor.authorKo, Joon-
dc.contributor.author고준-
dc.date.accessioned2011-12-13T01:52:18Z-
dc.date.available2011-12-13T01:52:18Z-
dc.date.issued2001-
dc.identifier.urihttp://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=169448&flag=dissertation-
dc.identifier.urihttp://hdl.handle.net/10203/29724-
dc.description학위논문(석사) - 한국과학기술원 : 화학공학과, 2001.8, [ viii, 70 p. ]-
dc.description.abstractThe effect of hydrothermal treatment on the photocatalytic properties of titania and silica embedded titania synthesized by sol-gel process was investigated. The characterization of the prepared catalyst was carried out with XRD, TEM, SEM, FT-IR, $N_2$ Adsorption and ESR study. The photocatalytic activity of titania catalysts was investigated for the degradation of 4-chlorophenol whose concentration was measured by HPLC with UV detector. The transition from anatase phase to rutile phase was suppressed by hydrothermal treatment. When silica was embedded in titania, there was a significant decrease in the density of surface hydroxyl group, whose distributions, however, were not affected by hydrothermal treatment. It was observed that hydrothermal treatment seemed to induce the formation of paramagnetic species such as $Ti^{3+},ㆍO_2^-$ on titania surface. Hydrothermally treated sol-gel titania showed a better photo-catalytic activity for the degradation of 4-chlorophenol than the sol-gel titania without hydrothermal treatment. It was also confirmed that the incorporation of silica into titania increased the photocatalytic activity. Even if the anatase phase was believed to have a better photocatalytic activity, the rutile phase formed by calcining the hydrothermally treated sol-gel titania at a higher temperature showed no less photocatalytic activity than the anatase phase formed at a lower temperature. The enhancement of anatase phase and the formation of the active paramagnetic species by hydrothermal treatment were responsible for the greatly enhanced photocatalytic activity.eng
dc.languageeng-
dc.publisher한국과학기술원-
dc.subjecthydrothermal treatment-
dc.subjectphotocatalysis-
dc.subjectsol-gel synthsis-
dc.subjecttitania-
dc.subjectparamagnetic species-
dc.subject상자기성 물질-
dc.subject수열처리-
dc.subject졸젤 합성-
dc.subject광촉매-
dc.subject타이타니아-
dc.title(A) study on the effect of hydrothermal treatment on the photocatalytic properties of titania synthesized by sol-gel method-
dc.title.alternative타이타니아의 졸젤 합성 중 수열처리에 의한 광촉매적 성질 변화 연구-
dc.typeThesis(Master)-
dc.identifier.CNRN169448/325007-
dc.description.department한국과학기술원 : 화학공학과, -
dc.identifier.uid000993802-
dc.contributor.localauthorIhm, Son-Ki-
dc.contributor.localauthor임선기-
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CBE-Theses_Master(석사논문)
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