Photoinduced alpha-C-H Amination of Cyclic Amine Scaffolds Enabled by Polar-Radical Relay

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dc.contributor.authorLee, Wongyuko
dc.contributor.authorKim, Dongwookko
dc.contributor.authorSeo, Sangwonko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2022-06-17T01:00:44Z-
dc.date.available2022-06-17T01:00:44Z-
dc.date.created2022-05-06-
dc.date.issued2022-06-
dc.identifier.citationANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.61, no.25-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10203/296976-
dc.description.abstractHerein, we report a polar-radical relay strategy for alpha-C-H amination of cyclic amines with N-chloro-N-sodio-carbamates. The relay is initiated by in situ generation of cyclic iminium intermediate using N-iodosuccinimide (NIS) oxidant as an initiator, which then operates through a series of polar (addition and elimination) and radical (homolysis, hydrogen- and halogen atom transfer) reactions to enable the challenging C-N bond formation in a controlled manner. A broad range of alpha-amino cyclic amines were readily accessed with excellent regioselectivity, and the superb applicability was further demonstrated by functionalization of biologically relevant compounds.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titlePhotoinduced alpha-C-H Amination of Cyclic Amine Scaffolds Enabled by Polar-Radical Relay-
dc.typeArticle-
dc.identifier.wosid000786629400001-
dc.identifier.scopusid2-s2.0-85128607542-
dc.type.rimsART-
dc.citation.volume61-
dc.citation.issue25-
dc.citation.publicationnameANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.identifier.doi10.1002/anie.202202971-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorSeo, Sangwon-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorAmination-
dc.subject.keywordAuthorAmines-
dc.subject.keywordAuthorRadicals-
dc.subject.keywordAuthorReaction Mechanisms-
dc.subject.keywordAuthorSustainability-
dc.subject.keywordPlusN BOND FORMATION-
dc.subject.keywordPlusHYPERVALENT IODINE(III)-
dc.subject.keywordPlusNITROGEN-HETEROCYCLES-
dc.subject.keywordPlusC(SP(3))-H AMINATION-
dc.subject.keywordPlusNITRENE TRANSFER-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusAMIDATION-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusRING-
dc.subject.keywordPlusDERIVATIVES-
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