DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Cho, EunAe | - |
dc.contributor.advisor | 조은애 | - |
dc.contributor.author | Kim, Ki Hyun | - |
dc.date.accessioned | 2022-04-21T19:32:13Z | - |
dc.date.available | 2022-04-21T19:32:13Z | - |
dc.date.issued | 2021 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=949124&flag=dissertation | en_US |
dc.identifier.uri | http://hdl.handle.net/10203/295468 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 신소재공학과, 2021.2,[xi, 63 p. :] | - |
dc.description.abstract | Development of highly active and durable catalysts to reduce usage of iridium for oxygen evolution reaction (OER) is essential for cost-effective hydrogen production by polymer electrolyte membrane water electrolysis. Herein, we reported Cu-Ir nanotubes (Cu-Ir NTs) with thin layer of 2 nm derived by following process, synthesis of 43 nm thickness of Cu nanowire templates, synthesis of 3.2 nm Ir shell layer on Cu core nanowire, and removing certain amount of Cu core nanowire by acid treatment. Through x-ray photoelectron spectroscopy (XPS), it was revealed that introduced Cu in Ir nanotubes change binding energy between iridium and oxygen intermediate, indicating of strong interaction between Cu and Ir. Furthermore, CO stripping revealed two times larger electrochemical surface area (ECSA) of Cu-Ir NTs (61.92 m$^2$/g) than those of Ir black (30.73 m$^2$/g). Due to copper-introduced effect and large ECSA, the Cu-Ir nanotubes exhibited outstanding OER mass activity (504 A/g) and specific activity (8.1 A/cm$^2$) than Ir black (200 A/g, 6.5 A/cm$^2$) in acid media. Also, Cu-Ir NTs showed superior durability in chronopotentiometry in current density of 10mA/cm$^2$ | - |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.subject | Oxygen evolution reaction▼ananotube catalyst▼aCu-Ir alloy | - |
dc.subject | 산소발생반응▼a나노 튜브 촉매▼a구리-이리듐 합금▼a활성 반응 표면적 | - |
dc.title | (A) study on Cu-Ir nanotube catalysts for oxygen evolution reaction | - |
dc.title.alternative | 산소발생반응용 구리-이리듐 합금 나노 튜브 촉매에 관한 연구 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 325007 | - |
dc.description.department | 한국과학기술원 :신소재공학과, | - |
dc.contributor.alternativeauthor | 김기현 | - |
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