Regio- and Stereoselective Functionalization Enabled by Bidentate Directing Groups

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Chelation-assisted C-H bond and alkene functionalization using bidentate directing groups offers an elegant and versatile approach to overcome regiocontrol issues by allowing the catalyst to come into close proximity with the targeted sites. In this personal account, we highlight our recent works in developing regio- and stereocontrolled functionalizations through transition-metal catalysis enabled by bidentate directing groups. We classify our results into two categories: (1) regioselective alkene functionalization using bidentate directing groups, and (2) asymmetric C-H functionalization using chiral bidentate directing groups. Furthermore, density functional theory studies to elucidate the origin of the regio- and stereoselectivity exerted by bidentate directing groups are discussed.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2021-12
Language
English
Article Type
Article
Citation

CHEMICAL RECORD, v.21, no.12, pp.3613 - 3627

ISSN
1527-8999
DOI
10.1002/tcr.202100117
URI
http://hdl.handle.net/10203/291445
Appears in Collection
CH-Journal Papers(저널논문)
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