DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Jeonghyo | ko |
dc.contributor.author | Kang, Bora | ko |
dc.contributor.author | Kim, Dongwook | ko |
dc.contributor.author | Lee, Jia | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2021-11-30T06:41:40Z | - |
dc.date.available | 2021-11-30T06:41:40Z | - |
dc.date.created | 2021-11-29 | - |
dc.date.created | 2021-11-29 | - |
dc.date.created | 2021-11-29 | - |
dc.date.issued | 2021-11 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.143, no.44, pp.18406 - 18412 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/289667 | - |
dc.description.abstract | We herein disclose the Cp*Co(III)(LX)-catalyzed amidative alkyl migration using 2,6-disubstituted phenyl azidoformates. Upon the cobalt- nitrenoid insertion toward the substituted ortho carbon, an arenium cationic species bearing a quaternary carbon is generated, and a subsequent alkyl migration process is suggested to occur through an unforeseen alkyl-walking mechanism. A quinolinol ligand of the cobalt catalyst system is proposed to facilitate the final product-releasing rearomatization process by serving as an internal base. This new mechanistic mode enabled both [1,2]- and [1,4]-alkyl rearrangements to allow the structural variation of N-heterocyclic compounds. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Cobalt-Nitrenoid Insertion-Mediated Amidative Carbon Rearrangement via Alkyl-Walking on Arenes | - |
dc.type | Article | - |
dc.identifier.wosid | 000718279300008 | - |
dc.identifier.scopusid | 2-s2.0-85118778201 | - |
dc.type.rims | ART | - |
dc.citation.volume | 143 | - |
dc.citation.issue | 44 | - |
dc.citation.beginningpage | 18406 | - |
dc.citation.endingpage | 18412 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/jacs.1c10138 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.contributor.nonIdAuthor | Lee, Jeonghyo | - |
dc.contributor.nonIdAuthor | Kang, Bora | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | C-H AMIDATION | - |
dc.subject.keywordPlus | 3-COMPOUND EQUILIBRATIONS | - |
dc.subject.keywordPlus | GAMMA-LACTAMS | - |
dc.subject.keywordPlus | ISOMERIZATION | - |
dc.subject.keywordPlus | AMINATION | - |
dc.subject.keywordPlus | AZIDES | - |
dc.subject.keywordPlus | MIGRATION | - |
dc.subject.keywordPlus | KINETICS | - |
dc.subject.keywordPlus | INDOLES | - |
dc.subject.keywordPlus | ARYL | - |
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