Physicochemical Understanding of the Impact of Pore Environment and Species of Adsorbates on Adsorption Behaviour

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For a better design of adsorbents, it is important to know the intermolecular interaction among adsorbates and host material, leading to improved guest selectivity and uptake capacity. In this study, we demonstrate the influence of the interaction among adsorbates and substrate, controlled by the pore environment and species of adsorbates, on the adsorption behaviour. We report the unique CO2 adsorption behaviour of MOF-205 due to distinct pore geometry. The precise analysis through gas-adsorption crystallography with molecular simulation shows that capillary condensation of CO2 in MOF-205 occurs preferentially in the large dodecahedral pore rather than the small tetrahedral pore, because the interaction of CO2 with MOF-205 framework is weaker than that among CO2 molecules, while Ar and N-2 are sequentially filled into two different pores of MOF-205 according to their size. Comparison of the materials with different pore environments reveals that the relative strength of the adsorbate-adsorbate and adsorbate-substrate interaction gives rise to different shapes of isotherms.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2021-09
Language
English
Article Type
Article
Citation

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.60, no.37, pp.20504 - 20510

ISSN
1433-7851
DOI
10.1002/anie.202107897
URI
http://hdl.handle.net/10203/287619
Appears in Collection
CH-Journal Papers(저널논문)MS-Journal Papers(저널논문)
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