DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Sewon | ko |
dc.contributor.author | Jeong, Seo Yeong | ko |
dc.contributor.author | Lee, Tae Kyung | ko |
dc.contributor.author | Park, Min Woo | ko |
dc.contributor.author | Lim, Hyeong Yong | ko |
dc.contributor.author | Sung, Jaekyung | ko |
dc.contributor.author | Cho, Jaephil | ko |
dc.contributor.author | Kwak, Sang Kyu | ko |
dc.contributor.author | Hong, Sung You | ko |
dc.contributor.author | Choi, Nam-Soon | ko |
dc.date.accessioned | 2021-08-20T06:30:09Z | - |
dc.date.available | 2021-08-20T06:30:09Z | - |
dc.date.created | 2021-08-20 | - |
dc.date.created | 2021-08-20 | - |
dc.date.created | 2021-08-20 | - |
dc.date.created | 2021-08-20 | - |
dc.date.created | 2021-08-20 | - |
dc.date.issued | 2021-02 | - |
dc.identifier.citation | NATURE COMMUNICATIONS, v.12, no.1 | - |
dc.identifier.issn | 2041-1723 | - |
dc.identifier.uri | http://hdl.handle.net/10203/287261 | - |
dc.description.abstract | Solid electrolyte interphases generated using electrolyte additives are key for anode-electrolyte interactions and for enhancing the lithium-ion battery lifespan. Classical solid electrolyte interphase additives, such as vinylene carbonate and fluoroethylene carbonate, have limited potential for simultaneously achieving a long lifespan and fast chargeability in high-energy-density lithium-ion batteries (LIBs). Here we report a next-generation synthetic additive approach that allows to form a highly stable electrode-electrolyte interface architecture from fluorinated and silylated electrolyte additives; it endures the lithiation-induced volume expansion of Si-embedded anodes and provides ion channels for facile Li-ion transport while protecting the Ni-rich LiNi0.8Co0.1Mn0.1O2 cathodes. The retrosynthetically designed solid electrolyte interphase-forming additives, 5-methyl-4-((trifluoromethoxy)methyl)-1,3-dioxol-2-one and 5-methyl-4-((trimethylsilyloxy)methyl)-1,3-dioxol-2-one, provide spatial flexibility to the vinylene carbonate-derived solid electrolyte interphase via polymeric propagation with the vinyl group of vinylene carbonate. The interface architecture from the synthesized vinylene carbonate-type additive enables high-energy-density LIBs with 81.5% capacity retention after 400 cycles at 1C and fast charging capability (1.9% capacity fading after 100 cycles at 3C). Interface architecture generated from electrolyte additives is a key element for high performance lithium-ion batteries. Here, the authors present that a stable and spatially deformable solid electrolyte interphase mitigates interfacial degradation of Si-embedded anodes and Ni-rich cathodes. | - |
dc.language | English | - |
dc.publisher | NATURE RESEARCH | - |
dc.title | Replacing conventional battery electrolyte additives with dioxolone derivatives for high-energy-density lithium-ion batteries | - |
dc.type | Article | - |
dc.identifier.wosid | 000617500200011 | - |
dc.identifier.scopusid | 2-s2.0-85100599144 | - |
dc.type.rims | ART | - |
dc.citation.volume | 12 | - |
dc.citation.issue | 1 | - |
dc.citation.publicationname | NATURE COMMUNICATIONS | - |
dc.identifier.doi | 10.1038/s41467-021-21106-6 | - |
dc.contributor.localauthor | Choi, Nam-Soon | - |
dc.contributor.nonIdAuthor | Park, Sewon | - |
dc.contributor.nonIdAuthor | Jeong, Seo Yeong | - |
dc.contributor.nonIdAuthor | Lee, Tae Kyung | - |
dc.contributor.nonIdAuthor | Park, Min Woo | - |
dc.contributor.nonIdAuthor | Lim, Hyeong Yong | - |
dc.contributor.nonIdAuthor | Sung, Jaekyung | - |
dc.contributor.nonIdAuthor | Cho, Jaephil | - |
dc.contributor.nonIdAuthor | Kwak, Sang Kyu | - |
dc.contributor.nonIdAuthor | Hong, Sung You | - |
dc.description.isOpenAccess | Y | - |
dc.type.journalArticle | Article | - |
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