Electrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis

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dc.contributor.authorJin, Seonghoko
dc.contributor.authorKim, Jinwooko
dc.contributor.authorKim, Dongwookko
dc.contributor.authorPark, Jung-Wooko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2021-07-06T02:50:37Z-
dc.date.available2021-07-06T02:50:37Z-
dc.date.created2021-07-05-
dc.date.created2021-07-05-
dc.date.issued2021-06-
dc.identifier.citationACS CATALYSIS, v.11, no.11, pp.6590 - 6595-
dc.identifier.issn2155-5435-
dc.identifier.urihttp://hdl.handle.net/10203/286419-
dc.description.abstractHerein, we describe the development of a Rh-catalyzed C-H acyloxylation under mild electrolytic conditions. Anodic oxidation of a key rhodacyclic carboxylate intermediate was found to enable the product-releasing C-O bond-forming reductive elimination process. An accumulation of carboxylate near the electrode surface was rationalized to further induce the desired C-O bond formation, allowing an ambient catalytic C-H oxygenation using stoichiometric amounts of readily accessible carboxylic acid coupling partners.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleElectrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis-
dc.typeArticle-
dc.identifier.wosid000661125100025-
dc.identifier.scopusid2-s2.0-85108194877-
dc.type.rimsART-
dc.citation.volume11-
dc.citation.issue11-
dc.citation.beginningpage6590-
dc.citation.endingpage6595-
dc.citation.publicationnameACS CATALYSIS-
dc.identifier.doi10.1021/acscatal.1c01670-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorKim, Jinwoo-
dc.contributor.nonIdAuthorPark, Jung-Woo-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorC-H activation-
dc.subject.keywordAuthorelectrochemistry-
dc.subject.keywordAuthorC-O bond formation-
dc.subject.keywordAuthorreductive elimination-
dc.subject.keywordAuthorhigh-valent pathway-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusCARBON-
dc.subject.keywordPlusBONDS-
dc.subject.keywordPlusACYLOXYLATION-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusALCOHOL-
dc.subject.keywordPlusWATER-
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