DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jin, Seongho | ko |
dc.contributor.author | Kim, Jinwoo | ko |
dc.contributor.author | Kim, Dongwook | ko |
dc.contributor.author | Park, Jung-Woo | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2021-07-06T02:50:37Z | - |
dc.date.available | 2021-07-06T02:50:37Z | - |
dc.date.created | 2021-07-05 | - |
dc.date.created | 2021-07-05 | - |
dc.date.issued | 2021-06 | - |
dc.identifier.citation | ACS CATALYSIS, v.11, no.11, pp.6590 - 6595 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.uri | http://hdl.handle.net/10203/286419 | - |
dc.description.abstract | Herein, we describe the development of a Rh-catalyzed C-H acyloxylation under mild electrolytic conditions. Anodic oxidation of a key rhodacyclic carboxylate intermediate was found to enable the product-releasing C-O bond-forming reductive elimination process. An accumulation of carboxylate near the electrode surface was rationalized to further induce the desired C-O bond formation, allowing an ambient catalytic C-H oxygenation using stoichiometric amounts of readily accessible carboxylic acid coupling partners. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Electrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis | - |
dc.type | Article | - |
dc.identifier.wosid | 000661125100025 | - |
dc.identifier.scopusid | 2-s2.0-85108194877 | - |
dc.type.rims | ART | - |
dc.citation.volume | 11 | - |
dc.citation.issue | 11 | - |
dc.citation.beginningpage | 6590 | - |
dc.citation.endingpage | 6595 | - |
dc.citation.publicationname | ACS CATALYSIS | - |
dc.identifier.doi | 10.1021/acscatal.1c01670 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.contributor.nonIdAuthor | Kim, Jinwoo | - |
dc.contributor.nonIdAuthor | Park, Jung-Woo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | C-H activation | - |
dc.subject.keywordAuthor | electrochemistry | - |
dc.subject.keywordAuthor | C-O bond formation | - |
dc.subject.keywordAuthor | reductive elimination | - |
dc.subject.keywordAuthor | high-valent pathway | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | CARBON | - |
dc.subject.keywordPlus | BONDS | - |
dc.subject.keywordPlus | ACYLOXYLATION | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | ALCOHOL | - |
dc.subject.keywordPlus | WATER | - |
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