Electrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis

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Herein, we describe the development of a Rh-catalyzed C-H acyloxylation under mild electrolytic conditions. Anodic oxidation of a key rhodacyclic carboxylate intermediate was found to enable the product-releasing C-O bond-forming reductive elimination process. An accumulation of carboxylate near the electrode surface was rationalized to further induce the desired C-O bond formation, allowing an ambient catalytic C-H oxygenation using stoichiometric amounts of readily accessible carboxylic acid coupling partners.
Publisher
AMER CHEMICAL SOC
Issue Date
2021-06
Language
English
Article Type
Article
Citation

ACS CATALYSIS, v.11, no.11, pp.6590 - 6595

ISSN
2155-5435
DOI
10.1021/acscatal.1c01670
URI
http://hdl.handle.net/10203/286419
Appears in Collection
CH-Journal Papers(저널논문)
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