DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Seongwoo | ko |
dc.contributor.author | Lee, Ha-Eun | ko |
dc.contributor.author | Suh, Jong-Min | ko |
dc.contributor.author | Lim, Mi Hee | ko |
dc.contributor.author | Kim, Min | ko |
dc.date.accessioned | 2020-12-29T08:10:05Z | - |
dc.date.available | 2020-12-29T08:10:05Z | - |
dc.date.created | 2020-12-08 | - |
dc.date.created | 2020-12-08 | - |
dc.date.issued | 2020-12 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.59, no.23, pp.17573 - 17582 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/279290 | - |
dc.description.abstract | A functionalized metal−organic framework (MOF) catalyst applied to the sequential one-pot oxidation of alcohols to carboxylic acids controls the presence of a heterogeneous catalyst. The conversion of alcohols to aldehydes was acquired through aerobic oxidation using a well-known amino-oxy radical-functionalized MOF. In the same flask, a simple filtration of the radical MOF with mild heating of the solution completely altered the reaction media, providing radical scavenger-free conditions suitable for the autoxidation of the aldehydes formed in the first step to carboxylic acids. The mutually exclusive radical-catalyzed aerobic oxidation (the first step with MOF) and radical-inhibited autoxidation (the second step without MOF) are sequentially achieved in a one-pot manner. Overall, we demonstrate a powerful and efficient method for the sequential oxidation of alcohols to carboxylic acids by employing a readily functionalizable heterogeneous MOF. In addition, our MOF in-and-out method can be utilized in an environmentally friendly way for the oxidation of alcohols to carboxylic acids of industrial and economic value with broad functional group tolerance, including 2,5-furandicarboxylic acid and 1 4-benzenedicarboxylic acid with good yield and reusability. Furthermore MOF-TEMPO as an antioxidative stabilizer, prevents the undesired oxidation of aldehydes, and the perfect “recoverability” of such a reactive MOF requires a re-evaluation of the advantages of MOFs from heterogeneity in catalytic and related applications. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Sequential connection of mutually exclusive catalytic reactions by a method controlling the presence of an MOF catalyst: One-pot oxidation of alcohols to carboxylic acids | - |
dc.type | Article | - |
dc.identifier.wosid | 000599190300086 | - |
dc.identifier.scopusid | 2-s2.0-85097581751 | - |
dc.type.rims | ART | - |
dc.citation.volume | 59 | - |
dc.citation.issue | 23 | - |
dc.citation.beginningpage | 17573 | - |
dc.citation.endingpage | 17582 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/acs.inorgchem.0c02809 | - |
dc.contributor.localauthor | Lim, Mi Hee | - |
dc.contributor.nonIdAuthor | Kim, Seongwoo | - |
dc.contributor.nonIdAuthor | Lee, Ha-Eun | - |
dc.contributor.nonIdAuthor | Kim, Min | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | SELECTIVE AEROBIC OXIDATION | - |
dc.subject.keywordPlus | NITROXYL RADICALS | - |
dc.subject.keywordPlus | BENZYLIC ALCOHOLS | - |
dc.subject.keywordPlus | AROMATIC ALCOHOLS | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | TEMPO | - |
dc.subject.keywordPlus | ALDEHYDES | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | SALTS | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.