Effects of Propylene Oxide End Capping on Amination of Polyalkylene Glycols

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Polyalkylene glycols with two different end-capping groups of ethylene oxide (EO) and propylene oxide (PO) were used for amination to produce polyetheramine (PEA) on cobalt-based catalysts. Although it is known that the amination of secondary alcohol is more difficult than that of primary alcohol, PO end-capped block copolymers showed remarkably enhanced activity toward PEA and selectivity toward the primary amine compared to EO end-capped block copolymers.
Publisher
AMER CHEMICAL SOC
Issue Date
2020-10
Language
English
Article Type
Article
Citation

ACS OMEGA, v.5, no.41, pp.26545 - 26550

ISSN
2470-1343
DOI
10.1021/acsomega.0c03295
URI
http://hdl.handle.net/10203/277913
Appears in Collection
CBE-Journal Papers(저널논문)
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