DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Jooyeon | ko |
dc.contributor.author | Satheeshkumar, Chinnadurai | ko |
dc.contributor.author | Yu, Hyun Jung | ko |
dc.contributor.author | Kim, Seongwoo | ko |
dc.contributor.author | Lee, Jong Suk | ko |
dc.contributor.author | Seo, Myungeun | ko |
dc.contributor.author | Kim, Min | ko |
dc.date.accessioned | 2020-10-29T08:55:07Z | - |
dc.date.available | 2020-10-29T08:55:07Z | - |
dc.date.created | 2020-10-26 | - |
dc.date.created | 2020-10-26 | - |
dc.date.created | 2020-10-26 | - |
dc.date.issued | 2020-09 | - |
dc.identifier.citation | ACS APPLIED NANO MATERIALS, v.3, no.9, pp.9356 - 9362 | - |
dc.identifier.issn | 2574-0970 | - |
dc.identifier.uri | http://hdl.handle.net/10203/277031 | - |
dc.description.abstract | Fine-tuning and pore environment control of covalently connected metal-organic framework (MOF) and mixed-matrix membrane (MMM) composite materials were achieved. Core-shell-type, dual-functionalized, zirconium-based MOFs were prepared through a postsynthetic ligand exchange (PSE) process, and active vinyl functionalities on the surface of MOF nanoparticles were utilized for polymerization by forming interfacial-covalent connections between MOF nanoparticles and polymeric membranes via thiol-ene click photopolymerization. The target functionality of the MOF pore originated from the parent MOFs, allowing pore engineering of the MOF-MMM composite materials. A series of defect-free, interface-controlled, and core-functionalized MOF-MMMs were prepared through the present methodology, and the NO2-functionalized/covalently connected MOF-MMM showed the highest CO2 permeability and solubility without loss of selectivity. This facile and versatile approach will be useful for the fabrication of functional MOF nanoparticle-based membranes for various applications, such as catalysis and separation. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Pore Engineering of Covalently Connected Metal-Organic Framework Nanoparticle-Mixed-Matrix Membrane Composites for Molecular Separation | - |
dc.type | Article | - |
dc.identifier.wosid | 000575846000082 | - |
dc.identifier.scopusid | 2-s2.0-85094813020 | - |
dc.type.rims | ART | - |
dc.citation.volume | 3 | - |
dc.citation.issue | 9 | - |
dc.citation.beginningpage | 9356 | - |
dc.citation.endingpage | 9362 | - |
dc.citation.publicationname | ACS APPLIED NANO MATERIALS | - |
dc.identifier.doi | 10.1021/acsanm.0c01982 | - |
dc.contributor.localauthor | Seo, Myungeun | - |
dc.contributor.nonIdAuthor | Lee, Jooyeon | - |
dc.contributor.nonIdAuthor | Satheeshkumar, Chinnadurai | - |
dc.contributor.nonIdAuthor | Yu, Hyun Jung | - |
dc.contributor.nonIdAuthor | Kim, Seongwoo | - |
dc.contributor.nonIdAuthor | Lee, Jong Suk | - |
dc.contributor.nonIdAuthor | Kim, Min | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | metal-organic frameworks | - |
dc.subject.keywordAuthor | mixed-matrix membranes | - |
dc.subject.keywordAuthor | MOF nanoparticle | - |
dc.subject.keywordAuthor | postsynthetic exchange | - |
dc.subject.keywordAuthor | pore-engineering | - |
dc.subject.keywordPlus | POSTSYNTHETIC LIGAND-EXCHANGE | - |
dc.subject.keywordPlus | UIO-66 | - |
dc.subject.keywordPlus | MOF | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | NMOF | - |
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