Au(I)-Catalyzed Cyclization of Epoxyalkynes to Allylic Alcohol Containing Spiroketals and Application to the Total Synthesis of (-)-Alotaketal A
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Lee, Jaeyeon | ko |
| dc.contributor.author | Kim, Jiheon | ko |
| dc.contributor.author | Lee, Hee-Yoon | ko |
| dc.date.accessioned | 2020-06-30T09:20:05Z | - |
| dc.date.available | 2020-06-30T09:20:05Z | - |
| dc.date.created | 2020-06-12 | - |
| dc.date.created | 2020-06-12 | - |
| dc.date.issued | 2020-06 | - |
| dc.identifier.citation | ORGANIC LETTERS, v.22, no.11, pp.4073 - 4077 | - |
| dc.identifier.issn | 1523-7060 | - |
| dc.identifier.uri | http://hdl.handle.net/10203/275063 | - |
| dc.description.abstract | A gold-catalyzed tandem spiroketalization of epoxyalkynes accompanied by epoxide rearrangement into the corresponding allylic alcohol was developed for the construction of functionalized spiroketals. This new synthetic methodology for unsaturated spiroketals warranted a facile total synthesis of alotaketal A from carvone via a corresponding epoxyalkyne precursor. | - |
| dc.language | English | - |
| dc.publisher | AMER CHEMICAL SOC | - |
| dc.title | Au(I)-Catalyzed Cyclization of Epoxyalkynes to Allylic Alcohol Containing Spiroketals and Application to the Total Synthesis of (-)-Alotaketal A | - |
| dc.type | Article | - |
| dc.identifier.wosid | 000538848600006 | - |
| dc.identifier.scopusid | 2-s2.0-85085626590 | - |
| dc.type.rims | ART | - |
| dc.citation.volume | 22 | - |
| dc.citation.issue | 11 | - |
| dc.citation.beginningpage | 4073 | - |
| dc.citation.endingpage | 4077 | - |
| dc.citation.publicationname | ORGANIC LETTERS | - |
| dc.identifier.doi | 10.1021/acs.orglett.0c01130 | - |
| dc.contributor.localauthor | Lee, Hee-Yoon | - |
| dc.description.isOpenAccess | N | - |
| dc.type.journalArticle | Article | - |
| dc.subject.keywordPlus | GOLD CATALYSIS SYNTHESIS | - |
| dc.subject.keywordPlus | SESTERTERPENOIDS | - |
| dc.subject.keywordPlus | TRANSFORMATION | - |
| dc.subject.keywordPlus | ALDEHYDES | - |
| dc.subject.keywordPlus | ALKYNES | - |
| dc.subject.keywordPlus | SPONGE | - |
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