DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Changjun | ko |
dc.contributor.author | Lee, Jinhee | ko |
dc.contributor.author | Kim, Taehyoung | ko |
dc.contributor.author | Lim, Jaechang | ko |
dc.contributor.author | Park, Jeyoung | ko |
dc.contributor.author | Kim, Woo Youn | ko |
dc.contributor.author | Kim, Sang Youl | ko |
dc.date.accessioned | 2020-04-29T03:20:16Z | - |
dc.date.available | 2020-04-29T03:20:16Z | - |
dc.date.created | 2020-04-27 | - |
dc.date.created | 2020-04-27 | - |
dc.date.created | 2020-04-27 | - |
dc.date.issued | 2020-01 | - |
dc.identifier.citation | MOLECULES, v.25, no.2 | - |
dc.identifier.issn | 1420-3049 | - |
dc.identifier.uri | http://hdl.handle.net/10203/274046 | - |
dc.description.abstract | Here, we report the formation of homochiral supramolecular thin film from achiral molecules, by using circularly polarized light (CPL) only as a chiral source, on the condition that irradiation of CPL does not induce a photochemical change of the achiral molecules. Thin films of self-assembled structures consisting of chiral supramolecular fibrils was obtained from the triarylamine derivatives through evaporation of the self-assembled triarylamine solution. The homochiral supramolecular helices with the desired handedness was achieved by irradiation of circularly polarized visible light during the self-assembly process, and the chiral stability of supramolecular self-assembled product was achieved by photopolymerization of the diacetylene moieties at side chains of the building blocks, with irradiation of circularly polarized ultraviolet light. This work provides a novel methodology for the generation of homochiral supramolecular thin film from the corresponding achiral molecules. | - |
dc.language | English | - |
dc.publisher | MDPI | - |
dc.title | Homochiral Supramolecular Thin Film from Self-Assembly of Achiral Triarylamine Molecules by Circularly Polarized Light | - |
dc.type | Article | - |
dc.identifier.wosid | 000515381800164 | - |
dc.identifier.scopusid | 2-s2.0-85078189926 | - |
dc.type.rims | ART | - |
dc.citation.volume | 25 | - |
dc.citation.issue | 2 | - |
dc.citation.publicationname | MOLECULES | - |
dc.identifier.doi | 10.3390/molecules25020402 | - |
dc.contributor.localauthor | Kim, Woo Youn | - |
dc.contributor.localauthor | Kim, Sang Youl | - |
dc.contributor.nonIdAuthor | Park, Jeyoung | - |
dc.description.isOpenAccess | Y | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | homochirality | - |
dc.subject.keywordAuthor | self-assembly | - |
dc.subject.keywordAuthor | triarylamine | - |
dc.subject.keywordAuthor | circularly polarized light | - |
dc.subject.keywordAuthor | helical systems | - |
dc.subject.keywordAuthor | spontaneous symmetry breaking | - |
dc.subject.keywordPlus | CHIRAL-SYMMETRY-BREAKING | - |
dc.subject.keywordPlus | WEIGHT ORGANIC GELS | - |
dc.subject.keywordPlus | PATHWAY COMPLEXITY | - |
dc.subject.keywordPlus | AMPLIFICATION | - |
dc.subject.keywordPlus | CHEMOSENSORS | - |
dc.subject.keywordPlus | SERGEANTS | - |
dc.subject.keywordPlus | POLYMERS | - |
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