A rational strategy for the realization of chain-growth supramolecular polymerization

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dc.contributor.authorKang, Jiheongko
dc.contributor.authorMiyajima, Daigoko
dc.contributor.authorMori, Tadashiko
dc.contributor.authorInoue, Yoshihisako
dc.contributor.authorItoh, Yoshimitsuko
dc.contributor.authorAida, Takuzoko
dc.date.accessioned2020-03-19T03:21:56Z-
dc.date.available2020-03-19T03:21:56Z-
dc.date.created2020-03-05-
dc.date.created2020-03-05-
dc.date.issued2015-02-
dc.identifier.citationSCIENCE, v.347, no.6222, pp.646 - 651-
dc.identifier.issn0036-8075-
dc.identifier.urihttp://hdl.handle.net/10203/272832-
dc.description.abstractOver the past decade, major progress in supramolecular polymerization has had a substantial effect on the design of functional soft materials. However, despite recent advances, most studies are still based on a preconceived notion that supramolecular polymerization follows a step-growth mechanism, which precludes control over chain length, sequence, and stereochemical structure. Here we report the realization of chain-growth polymerization by designing metastable monomers with a shape-promoted intramolecular hydrogen-bonding network. The monomers are conformationally restricted from spontaneous polymerization at ambient temperatures but begin to polymerize with characteristics typical of a living mechanism upon mixing with tailored initiators. The chain growth occurs stereoselectively and therefore enables optical resolution of a racemic monomer.-
dc.languageEnglish-
dc.publisherAMER ASSOC ADVANCEMENT SCIENCE-
dc.titleA rational strategy for the realization of chain-growth supramolecular polymerization-
dc.typeArticle-
dc.identifier.wosid000349145200041-
dc.identifier.scopusid2-s2.0-84922356624-
dc.type.rimsART-
dc.citation.volume347-
dc.citation.issue6222-
dc.citation.beginningpage646-
dc.citation.endingpage651-
dc.citation.publicationnameSCIENCE-
dc.identifier.doi10.1126/science.aaa4249-
dc.contributor.localauthorKang, Jiheong-
dc.contributor.nonIdAuthorMiyajima, Daigo-
dc.contributor.nonIdAuthorMori, Tadashi-
dc.contributor.nonIdAuthorInoue, Yoshihisa-
dc.contributor.nonIdAuthorItoh, Yoshimitsu-
dc.contributor.nonIdAuthorAida, Takuzo-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusMICELLES-
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