DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kang, Jiheong | ko |
dc.contributor.author | Miyajima, Daigo | ko |
dc.contributor.author | Mori, Tadashi | ko |
dc.contributor.author | Inoue, Yoshihisa | ko |
dc.contributor.author | Itoh, Yoshimitsu | ko |
dc.contributor.author | Aida, Takuzo | ko |
dc.date.accessioned | 2020-03-19T03:21:56Z | - |
dc.date.available | 2020-03-19T03:21:56Z | - |
dc.date.created | 2020-03-05 | - |
dc.date.created | 2020-03-05 | - |
dc.date.issued | 2015-02 | - |
dc.identifier.citation | SCIENCE, v.347, no.6222, pp.646 - 651 | - |
dc.identifier.issn | 0036-8075 | - |
dc.identifier.uri | http://hdl.handle.net/10203/272832 | - |
dc.description.abstract | Over the past decade, major progress in supramolecular polymerization has had a substantial effect on the design of functional soft materials. However, despite recent advances, most studies are still based on a preconceived notion that supramolecular polymerization follows a step-growth mechanism, which precludes control over chain length, sequence, and stereochemical structure. Here we report the realization of chain-growth polymerization by designing metastable monomers with a shape-promoted intramolecular hydrogen-bonding network. The monomers are conformationally restricted from spontaneous polymerization at ambient temperatures but begin to polymerize with characteristics typical of a living mechanism upon mixing with tailored initiators. The chain growth occurs stereoselectively and therefore enables optical resolution of a racemic monomer. | - |
dc.language | English | - |
dc.publisher | AMER ASSOC ADVANCEMENT SCIENCE | - |
dc.title | A rational strategy for the realization of chain-growth supramolecular polymerization | - |
dc.type | Article | - |
dc.identifier.wosid | 000349145200041 | - |
dc.identifier.scopusid | 2-s2.0-84922356624 | - |
dc.type.rims | ART | - |
dc.citation.volume | 347 | - |
dc.citation.issue | 6222 | - |
dc.citation.beginningpage | 646 | - |
dc.citation.endingpage | 651 | - |
dc.citation.publicationname | SCIENCE | - |
dc.identifier.doi | 10.1126/science.aaa4249 | - |
dc.contributor.localauthor | Kang, Jiheong | - |
dc.contributor.nonIdAuthor | Miyajima, Daigo | - |
dc.contributor.nonIdAuthor | Mori, Tadashi | - |
dc.contributor.nonIdAuthor | Inoue, Yoshihisa | - |
dc.contributor.nonIdAuthor | Itoh, Yoshimitsu | - |
dc.contributor.nonIdAuthor | Aida, Takuzo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | MICELLES | - |
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