DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Kang, Jeung Ku | - |
dc.contributor.advisor | 강정구 | - |
dc.contributor.author | Jeong, Hee-Soo | - |
dc.date.accessioned | 2019-09-03T02:45:00Z | - |
dc.date.available | 2019-09-03T02:45:00Z | - |
dc.date.issued | 2019 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=843325&flag=dissertation | en_US |
dc.identifier.uri | http://hdl.handle.net/10203/266416 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 신소재공학과, 2019.2,[ii, 40 p. :] | - |
dc.description.abstract | This thesis discusses electrochemical catalysis in enery conversion technology. The Oxygen Evolution Reaction (OER) is considered most importantly in electrochemical catalysis. Huge research has been progressed to improve catalytic activity because basically sluggish OER determines the various reaction rate. Two strategies to improve electrocatalytic activity are increasing the number of active sites and intrinsic activity of active sites. In this research, to increase the number of active sites, Zeolitic Imidazolate Frameworks were utilized as nano-reactor for synthesis of non-aggregated nanoparticle. In addition, to increase the intrinsic activity, Cu-Co bimetallic complex was designed. Non-aggregated Cu-Co bimetallic complex nanoparticle was successfully synthesized on ZIF-8 shell using ZIF67@ZIF8 core shell. To verifying catalytic activity for OER, electrochemical analysis was conducted. Cu-Co bimetallic complex showed up to 48mV reduced overpotential compared to catalyst without copper and confirmed that catalytic activity was improved. | - |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.subject | oxygen evolution reaction▼acatalytic activity▼aZeolitic Imidazolate Frameworks(ZIFs)▼ananoreactor▼ananoparticle▼aCu-Co bimetallic complex▼acoreshell | - |
dc.subject | 산소발생반응▼a촉매 활성도▼a제올라이트이미다졸레이트골격체▼a나노반응용기▼a나노입자▼a구리-코발트 이중금속 복합체▼a코어쉘 | - |
dc.title | Design of multimetallic complex derived from metal-organic frameworks for electrocatalysis | - |
dc.title.alternative | 전기촉매작용을 위한 금속유기구조체로부터 파생된 다금속복합체 설계에 관한 연구 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 325007 | - |
dc.description.department | 한국과학기술원 :신소재공학과, | - |
dc.contributor.alternativeauthor | 정희수 | - |
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