Synthesis of crystalline microporous aluminophosphates using organic sulfonium compounds and multi-ammonium surfactants as structure-directing agents유기 설포늄 화합물과 다중 암모늄 계면활성제를 구조 유도 물질로 이용한 결정성 미세다공성 알루미노포스페이트의 합성에 관한 연구

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dc.contributor.advisorRyoo, Ryong-
dc.contributor.advisor유룡-
dc.contributor.authorLee, Sungjune-
dc.date.accessioned2019-08-25T02:50:29Z-
dc.date.available2019-08-25T02:50:29Z-
dc.date.issued2018-
dc.identifier.urihttp://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=734467&flag=dissertationen_US
dc.identifier.urihttp://hdl.handle.net/10203/265468-
dc.description학위논문(박사) - 한국과학기술원 : 화학과, 2018.2,[vi, 83 p. :]-
dc.description.abstractThe structure-directing agents play a key role in determining the pore structure of crystalline microporous aluminophosphates (AlPOs), and the organic amine and ammonium molecules have been widely used. In the present thesis, AlPOs were synthesized using multi-ammonium surfactants and organic sulfonium-based compounds as structure-directing agents. In the AlPO synthesis using multi-ammonium surfactants, meso-level morphologies including nanosheet or nanosponge were produced through the self-assembly of surfactant molecules into micelles. At the same time, ATO-type microporous framework was constructed by ammonium functionalities in the head group of surfactant. It was revealed that the organic sulfide molecules can perform structure-directing function for AlPOs by being protonated into sulfoniums in the AlPO synthesis gel, however, final product was a mixture of AFI-type AlPO and non-porous aluminophosphate due to the weak basicity of sulfide molecules. Instead, ATS-type AlPO can be produced in a single phase with extended synthesis domain when using the triphenylsulfonium molecule as a structure-directing agent.-
dc.languageeng-
dc.publisher한국과학기술원-
dc.subjectcrystalline microporous aluminophosphate▼astructure-directing agent▼aorganic sulfonium▼aorganic sulfide▼amulti-ammonium surfactant-
dc.subject결정성 미세다공성 알루미노포스페이트▼a구조 유도 물질▼a유기 설포늄▼a유기 설파이드▼a다중 암모늄 계면활성제-
dc.titleSynthesis of crystalline microporous aluminophosphates using organic sulfonium compounds and multi-ammonium surfactants as structure-directing agents-
dc.title.alternative유기 설포늄 화합물과 다중 암모늄 계면활성제를 구조 유도 물질로 이용한 결정성 미세다공성 알루미노포스페이트의 합성에 관한 연구-
dc.typeThesis(Ph.D)-
dc.identifier.CNRN325007-
dc.description.department한국과학기술원 :화학과,-
dc.contributor.alternativeauthor이승준-
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