Self-Assembly of a beta-Peptide Foldamer: The Role of the Surfactant in Three-Dimensional Shape Selection

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The effect of a small ionic surfactant, cetyltrimethylammonium bromide (CTAB), on the self-assembly of a beta-peptide has been systematically studied by using scanning electron microscopy, X-ray diffraction, selected area electron diffraction, and molecular dynamics (MD) simulations. The latter study suggested that the formation of asymmetric microcrystals may be due to the preferential adsorption of CTAB on {011} and (001) crystal faces. This work provides a plausible rationale for the characteristic 3D morphogenesis of foldectures and elucidates the interaction between the surfactant and organic building block molecules.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2019-05
Language
English
Article Type
Article
Citation

CHEMPLUSCHEM, v.84, no.5, pp.481 - 487

ISSN
2192-6506
DOI
10.1002/cplu.201900027
URI
http://hdl.handle.net/10203/263331
Appears in Collection
EEW-Journal Papers(저널논문)CH-Journal Papers(저널논문)
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