DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Yechan | ko |
dc.contributor.author | Lee, Kangjae | ko |
dc.contributor.author | Mathi, Gangadhar Rao | ko |
dc.contributor.author | Kim, Inwon | ko |
dc.contributor.author | Hong, Sungwoo | ko |
dc.date.accessioned | 2019-05-10T04:30:06Z | - |
dc.date.available | 2019-05-10T04:30:06Z | - |
dc.date.created | 2019-05-10 | - |
dc.date.created | 2019-05-10 | - |
dc.date.created | 2019-05-10 | - |
dc.date.issued | 2019-04 | - |
dc.identifier.citation | GREEN CHEMISTRY, v.21, no.8, pp.2082 - 2087 | - |
dc.identifier.issn | 1463-9262 | - |
dc.identifier.uri | http://hdl.handle.net/10203/261835 | - |
dc.description.abstract | Reported is a novel visible-light-enabled alkoxy radical ring-closure and pyridylation from N-alkenyloxypyridinium salts serving as both alkoxy radical precursors and heteroaryl sources. This strategy features a photoredox tandem radical process involving a sequential fragmentation of an N-alkoxypyridinium salt, a radical cyclization process, and a pyridylation process. This method exhibited broad substrate scope, good functional group compatibility, and metal-free mild conditions, offering a powerful synthetic tool for assembling various pyridine-tethered tetrahydrofurans and late-stage functionalization of complex biorelevant molecules. Moreover, radical cascade cyclization could be successfully achieved, leading to the synthesis of previously challenging and important pyridine-tethered bicyclic oxaspiro ring systems. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Visible-light-induced cascade radical ring-closure and pyridylation for the synthesis of tetrahydrofurans | - |
dc.type | Article | - |
dc.identifier.wosid | 000465398000023 | - |
dc.identifier.scopusid | 2-s2.0-85064638073 | - |
dc.type.rims | ART | - |
dc.citation.volume | 21 | - |
dc.citation.issue | 8 | - |
dc.citation.beginningpage | 2082 | - |
dc.citation.endingpage | 2087 | - |
dc.citation.publicationname | GREEN CHEMISTRY | - |
dc.identifier.doi | 10.1039/c9gc00414a | - |
dc.contributor.localauthor | Hong, Sungwoo | - |
dc.contributor.nonIdAuthor | Mathi, Gangadhar Rao | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | PHOTOREDOX CATALYSIS | - |
dc.subject.keywordPlus | METAL-FREE | - |
dc.subject.keywordPlus | STEREOSELECTIVE-SYNTHESIS | - |
dc.subject.keywordPlus | PHOTOCATALYZED SYNTHESIS | - |
dc.subject.keywordPlus | BOND FRAGMENTATION | - |
dc.subject.keywordPlus | ARYL BROMIDES | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | QUINOLINONES | - |
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