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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Ni-Mediated Generation of "CN" Unit from Formamide and Its Catalysis in the Cyanation Reactions

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dc.contributor.authorYang, Luoko
dc.contributor.authorLiu, Yu-Tingko
dc.contributor.authorPARK, YOONSUko
dc.contributor.authorPark, Sung-Wooko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2019-05-02T02:30:02Z-
dc.date.available2019-05-02T02:30:02Z-
dc.date.created2019-04-29-
dc.date.created2019-04-29-
dc.date.created2019-04-29-
dc.date.issued2019-04-
dc.identifier.citationACS CATALYSIS, v.9, no.4, pp.3360 - 3365-
dc.identifier.issn2155-5435-
dc.identifier.urihttp://hdl.handle.net/10203/261697-
dc.description.abstractThe in situ generation of a "cyano" unit from readily available organic precursors is of high interest in synthetic chemistry. Herein, we report the first example of Ni-mediated dehydration of formamide to form "CN" and its subsequent catalytic applications in the hydrocyanation of alkynes and cyanation of aryl halides. Formamide can serve as a convenient source for the nitrile unit, in that it releases water as the only byproduct.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleNi-Mediated Generation of "CN" Unit from Formamide and Its Catalysis in the Cyanation Reactions-
dc.typeArticle-
dc.identifier.wosid000464075700064-
dc.identifier.scopusid2-s2.0-85063130009-
dc.type.rimsART-
dc.citation.volume9-
dc.citation.issue4-
dc.citation.beginningpage3360-
dc.citation.endingpage3365-
dc.citation.publicationnameACS CATALYSIS-
dc.identifier.doi10.1021/acscatal.8b05111-
dc.contributor.localauthorPARK, YOONSU-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorYang, Luo-
dc.contributor.nonIdAuthorLiu, Yu-Ting-
dc.contributor.nonIdAuthorPark, Sung-Woo-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorcyano source-
dc.subject.keywordAuthorformamide-
dc.subject.keywordAuthorNi catalyst-
dc.subject.keywordAuthorhydrocyanation-
dc.subject.keywordAuthoralkynes-
dc.subject.keywordAuthoraryl halides-
dc.subject.keywordPlusELECTROPHILIC CYANATION-
dc.subject.keywordPlusAMMONIUM IODIDE-
dc.subject.keywordPlusARYL-
dc.subject.keywordPlusNITRILES-
dc.subject.keywordPlusBOND-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusEFFICIENT-
dc.subject.keywordPlusINDOLES-
dc.subject.keywordPlusCYANIDE-
dc.subject.keywordPlusHYDROCYANATION-
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CH-Journal Papers(저널논문)
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