DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이승준 | ko |
dc.contributor.author | 용석민 | ko |
dc.contributor.author | 김동석 | ko |
dc.contributor.author | 김도경 | ko |
dc.date.accessioned | 2019-04-16T02:51:39Z | - |
dc.date.available | 2019-04-16T02:51:39Z | - |
dc.date.created | 2013-07-17 | - |
dc.date.issued | 2011-05-27 | - |
dc.identifier.citation | 2011 한국재료학회 춘계학술발표대회 및 제 20회 신소재 심포지엄 | - |
dc.identifier.uri | http://hdl.handle.net/10203/260062 | - |
dc.description.abstract | Cobalt- free LaxSr4-xFe6O13 (0<x<2) oxide have been synthesized and investigated as a potential cathode material for solid oxide fuel cells (SOFCs). Sr4Fe6O13 consists of alternating perovskite layers (Sr4Fe2O8) containing iron cations in octahedral oxygen coordination and Fe4O5 layers where iron cations have 5-fold coordination of two types-square pyramids and trigonal bipyramids. Our prelinlinary electrochemical testes of pristine Sr4Fe6O13 show a rather high area specific resistance (0.47 Ocm2 at 700oC) for ~20 μm thick layers with CGO electrolyte. The electrochemical performances are improved by La addition up to x=1 (La1Sr3Fe6013 , 0.06 Ocm2 at 700oC) . In addition, thermal expansion coefficient (TEC) values of La1Sr3Fe6013 specimen demonstrated 15.1 x10-6 oC-1 in the range of 25-900oC, which provides good thermal expansion compatibility with the CGO electrolyte. An electrolyte supported (300-μm-thick) single-cell configuration of La1Sr3Fe6O13/CGO/Ni-CGO delivered a maximum power density of 584 mWcm-2 at 700oC. In addition, an anode supported single cell by YSZ electolyte (10-μm-thick) with a porous CGO interlayer between the cathode and the electrolyte to avoid undesired interfacial reactions exhibited 1,517 m Wcm-2 at 800oC. The unique composition of La1Sr3Fe6O13 with low theral expansion coefficient and higher electrochemical properties could be a good cathode candidate for intermediate temperature SOFCs with CGO and YSZ electrolyte. | - |
dc.language | Korean | - |
dc.publisher | 한국재료학회 | - |
dc.title | Development of cobalt-free LaxSr4-xFe6O13 (0<x<2) Intergrowth Cathode Material for Solid Oxide Fuel Cells | - |
dc.type | Conference | - |
dc.type.rims | CONF | - |
dc.citation.publicationname | 2011 한국재료학회 춘계학술발표대회 및 제 20회 신소재 심포지엄 | - |
dc.identifier.conferencecountry | KO | - |
dc.contributor.localauthor | 김도경 | - |
dc.contributor.nonIdAuthor | 이승준 | - |
dc.contributor.nonIdAuthor | 용석민 | - |
dc.contributor.nonIdAuthor | 김동석 | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.