APSe(6) (A = k, Rb, and Cs): Polymeric selenophosphates with reversible phase-change properties

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dc.contributor.authorChung, Iko
dc.contributor.authorDo, Jko
dc.contributor.authorCanlas, CGko
dc.contributor.authorWeliky, DPko
dc.contributor.authorKanatzidis, MGko
dc.date.accessioned2019-04-15T16:32:20Z-
dc.date.available2019-04-15T16:32:20Z-
dc.date.created2013-05-06-
dc.date.issued2004-05-
dc.identifier.citationINORGANIC CHEMISTRY, v.43, no.9, pp.2762 - 2764-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10203/255898-
dc.description.abstractThe ternary alkali selenophosphates KPSe6 and RbPSe6 crystallize in the polar orthorhombic space group Pca2(1) with a = 11.7764(17) Angstrom, b = 6.8580(10) Angstrom, c = 11.4596(16) Angstrom, and Z = 4 for RbPSe6. CsPSe6 crystallizes in the monoclinic space group P2/n with a = 6.877(3) Angstrom, b = 12.713(4) Angstrom, c = 11.242(4) Angstrom, beta = 92.735(7)degrees, and Z= 4. All compounds feature the one-dimensional infinite chain of [PSe2(Se)(4)(-)], where each P atom is connected with Se-4(2-) bridge. These compounds show reversible glass-crystal transition, and P-31 NMR data suggest that crystallization and infinite [PSe6-] chain formation are coupled processes.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectMETAL POLYSELENOPHOSPHATE FLUXES-
dc.subjectANION-
dc.subjectFRAGMENTS-
dc.subjectBONDS-
dc.titleAPSe(6) (A = k, Rb, and Cs): Polymeric selenophosphates with reversible phase-change properties-
dc.typeArticle-
dc.identifier.wosid000221168000003-
dc.identifier.scopusid2-s2.0-2142767362-
dc.type.rimsART-
dc.citation.volume43-
dc.citation.issue9-
dc.citation.beginningpage2762-
dc.citation.endingpage2764-
dc.citation.publicationnameINORGANIC CHEMISTRY-
dc.identifier.doi10.1021/ic035448q-
dc.contributor.localauthorChung, I-
dc.contributor.nonIdAuthorDo, J-
dc.contributor.nonIdAuthorCanlas, CG-
dc.contributor.nonIdAuthorWeliky, DP-
dc.contributor.nonIdAuthorKanatzidis, MG-
dc.type.journalArticleArticle-
dc.subject.keywordPlusMETAL POLYSELENOPHOSPHATE FLUXES-
dc.subject.keywordPlusANION-
dc.subject.keywordPlusFRAGMENTS-
dc.subject.keywordPlusBONDS-
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