DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jung, Joo Young | ko |
dc.contributor.author | Karadas, Ferdi | ko |
dc.contributor.author | Zulfiqar, Sonia | ko |
dc.contributor.author | Deniz, Erhan | ko |
dc.contributor.author | Aparicio, Santiago | ko |
dc.contributor.author | Atilhan, Mert | ko |
dc.contributor.author | Yavuz, Cafer T | ko |
dc.contributor.author | Han, Seung Min J. | ko |
dc.date.accessioned | 2019-04-15T15:32:14Z | - |
dc.date.available | 2019-04-15T15:32:14Z | - |
dc.date.created | 2013-07-26 | - |
dc.date.issued | 2013-04 | - |
dc.identifier.citation | PHYSICAL CHEMISTRY CHEMICAL PHYSICS, v.15, no.34, pp.14319 - 14327 | - |
dc.identifier.issn | 1463-9076 | - |
dc.identifier.uri | http://hdl.handle.net/10203/255055 | - |
dc.description.abstract | Porous network structures (e. g. metal-organic frameworks, MOFs) show considerable potential in dethroning monoethanol amine (MEA) from being the dominant scrubber for CO2 at the fossil-fuel-burning power generators. In contrast to their promise, structural stability and high-pressure behavior of MOFs are not well documented. We herein report moisture stability, mechanical properties and high-pressure compression on a model MOF structure, MOF-5. Our results show that MOF-5 can endure all tested pressures (0-225 bar) without losing its structural integrity, however, its moist air stability points at a 3.5 hour safety window (at 21.6 degrees C and 49% humidity) for an efficient CO2 capture. Isosteric heats of CO2 adsorption at high pressures show moderate interaction energy between CO2 molecules and the MOF-5 sorbent, which combined with the large sorption ability of MOF-5 in the studied pressure-temperature ranges show the viability of this sorbent for CO2 capturing purposes. The combination of the physicochemical methods we used suggests a generalized analytical standard for measuring viability in CO2 capture operations. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | METAL-ORGANIC FRAMEWORKS | - |
dc.subject | MAGNETIC SUSPENSION BALANCE | - |
dc.subject | CARBON-DIOXIDE | - |
dc.subject | ELASTOPLASTIC INDENTATION/CONTACT | - |
dc.subject | COORDINATION POLYMERS | - |
dc.subject | HYDROGEN ADSORPTION | - |
dc.subject | HIGH-CAPACITY | - |
dc.subject | STRESS-FIELD | - |
dc.subject | STORAGE | - |
dc.subject | METHANE | - |
dc.title | Limitations and high pressure behavior of MOF-5 for CO2 capture | - |
dc.type | Article | - |
dc.identifier.wosid | 000322725000021 | - |
dc.identifier.scopusid | 2-s2.0-84881393071 | - |
dc.type.rims | ART | - |
dc.citation.volume | 15 | - |
dc.citation.issue | 34 | - |
dc.citation.beginningpage | 14319 | - |
dc.citation.endingpage | 14327 | - |
dc.citation.publicationname | PHYSICAL CHEMISTRY CHEMICAL PHYSICS | - |
dc.identifier.doi | 10.1039/c3cp51768c | - |
dc.contributor.localauthor | Yavuz, Cafer T | - |
dc.contributor.localauthor | Han, Seung Min J. | - |
dc.contributor.nonIdAuthor | Jung, Joo Young | - |
dc.contributor.nonIdAuthor | Karadas, Ferdi | - |
dc.contributor.nonIdAuthor | Zulfiqar, Sonia | - |
dc.contributor.nonIdAuthor | Deniz, Erhan | - |
dc.contributor.nonIdAuthor | Aparicio, Santiago | - |
dc.contributor.nonIdAuthor | Atilhan, Mert | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | MAGNETIC SUSPENSION BALANCE | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | ELASTOPLASTIC INDENTATION/CONTACT | - |
dc.subject.keywordPlus | COORDINATION POLYMERS | - |
dc.subject.keywordPlus | HYDROGEN ADSORPTION | - |
dc.subject.keywordPlus | HIGH-CAPACITY | - |
dc.subject.keywordPlus | STRESS-FIELD | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | METHANE | - |
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