DC Field | Value | Language |
---|---|---|
dc.contributor.author | Seo, Myungeun | ko |
dc.contributor.author | Murphy, Christopher J. | ko |
dc.contributor.author | Hillmyer, Marc A. | ko |
dc.date.accessioned | 2019-04-15T15:12:39Z | - |
dc.date.available | 2019-04-15T15:12:39Z | - |
dc.date.created | 2013-07-27 | - |
dc.date.created | 2013-07-27 | - |
dc.date.created | 2013-07-27 | - |
dc.date.issued | 2013-07 | - |
dc.identifier.citation | ACS MACRO LETTERS, v.2, no.7, pp.617 - 620 | - |
dc.identifier.issn | 2161-1653 | - |
dc.identifier.uri | http://hdl.handle.net/10203/254783 | - |
dc.description.abstract | Using a simultaneous block polymerization/in situ cross-linking from a heterofunctional initiator approach, we produced a nanostructured and cross-linked block polymer in a single step from a ternary mixture of monomers and used it as a precursor for a cross-linked nanoporous material. Using 2-(benzylsulfanylthiocarbonylsulfanyl)ethanol as a heterofunctional initiator, simultaneous ring-opening transesterification polymerization of D,L-lactide in the presence of tin 2-ethylhexanoate as a catalyst and reversible addition-fragmentation chain transfer polymerization of styrene at 120 degrees C produced a polylactide-b-polystyrene (PLA-b-PS) block polymer. Incorporation of divinylbenzene in the polymerization mixture allowed in situ cross-linking during the simultaneous block polymerization to result in the cross-linked block polymer precursor in one step. This material was converted into cross-linked nanoporous polymer by etching PLA in a basic solution. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | One-Step Synthesis of Cross-Linked Block Polymer Precursor to a Nanoporous Thermoset | - |
dc.type | Article | - |
dc.identifier.wosid | 000322059300011 | - |
dc.identifier.scopusid | 2-s2.0-84880709852 | - |
dc.type.rims | ART | - |
dc.citation.volume | 2 | - |
dc.citation.issue | 7 | - |
dc.citation.beginningpage | 617 | - |
dc.citation.endingpage | 620 | - |
dc.citation.publicationname | ACS MACRO LETTERS | - |
dc.identifier.doi | 10.1021/mz400192f | - |
dc.contributor.localauthor | Seo, Myungeun | - |
dc.contributor.nonIdAuthor | Murphy, Christopher J. | - |
dc.contributor.nonIdAuthor | Hillmyer, Marc A. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | RING-OPENING POLYMERIZATION | - |
dc.subject.keywordPlus | ONE-POT SYNTHESIS | - |
dc.subject.keywordPlus | TRANSFER RADICAL POLYMERIZATION | - |
dc.subject.keywordPlus | DIBLOCK COPOLYMERS | - |
dc.subject.keywordPlus | MEDIATED POLYMERIZATION | - |
dc.subject.keywordPlus | CYCLIC ESTERS | - |
dc.subject.keywordPlus | MONOLITHS | - |
dc.subject.keywordPlus | SHELL | - |
dc.subject.keywordPlus | NANOSTRUCTURES | - |
dc.subject.keywordPlus | STYRENE | - |
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