DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Yoon-Jung | ko |
dc.contributor.author | Yoon, Yeokwon | ko |
dc.contributor.author | Lee, Hee Yoon | ko |
dc.date.accessioned | 2019-04-15T14:52:54Z | - |
dc.date.available | 2019-04-15T14:52:54Z | - |
dc.date.created | 2013-10-07 | - |
dc.date.issued | 2013-09 | - |
dc.identifier.citation | TETRAHEDRON, v.69, no.36, pp.7810 - 7816 | - |
dc.identifier.issn | 0040-4020 | - |
dc.identifier.uri | http://hdl.handle.net/10203/254496 | - |
dc.description.abstract | A stereoselective total synthesis of (+)-pentalenene was achieved through the tandem cycloaddition reaction of the allenyl diazo substrate prepared from (+)-citronellal. The initial intramolecular [2+3] cycloaddition reaction between the diazo functionality and the allenyl group produced the trimethylenemethane (TMM) intermediate after immediate loss of nitrogen molecule from the cycloaddition intermediate. Subsequent [2+3] cycloaddition of the TMM with olefin produced the angularly fused triquinane structure stereoselectively. (C) 2013 Elsevier Ltd. All rights reserved. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject | ANGULAR TRIQUINANES | - |
dc.subject | (+/-)-DEOXYPENTALENIC ACID | - |
dc.subject | TRIMETHYLENEMETHANE DIYLS | - |
dc.subject | (+/-)-PENTALENIC ACID | - |
dc.subject | RADICAL CYCLIZATION | - |
dc.subject | ORGANIC-SYNTHESIS | - |
dc.subject | NATURAL-PRODUCTS | - |
dc.subject | IDEAL SYNTHESIS | - |
dc.subject | PENTALENENE | - |
dc.subject | CYCLOADDITION | - |
dc.title | An asymmetric total synthesis of (+)-pentalenene | - |
dc.type | Article | - |
dc.identifier.wosid | 000322939900029 | - |
dc.identifier.scopusid | 2-s2.0-84880920805 | - |
dc.type.rims | ART | - |
dc.citation.volume | 69 | - |
dc.citation.issue | 36 | - |
dc.citation.beginningpage | 7810 | - |
dc.citation.endingpage | 7816 | - |
dc.citation.publicationname | TETRAHEDRON | - |
dc.identifier.doi | 10.1016/j.tet.2013.05.095 | - |
dc.contributor.localauthor | Lee, Hee Yoon | - |
dc.contributor.nonIdAuthor | Kim, Yoon-Jung | - |
dc.contributor.nonIdAuthor | Yoon, Yeokwon | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Stereoselective | - |
dc.subject.keywordAuthor | Total synthesis | - |
dc.subject.keywordAuthor | Triquinane | - |
dc.subject.keywordAuthor | Trimethylenemethane | - |
dc.subject.keywordAuthor | Tandem cycloaddition | - |
dc.subject.keywordPlus | ANGULAR TRIQUINANES | - |
dc.subject.keywordPlus | (+/-)-DEOXYPENTALENIC ACID | - |
dc.subject.keywordPlus | TRIMETHYLENEMETHANE DIYLS | - |
dc.subject.keywordPlus | (+/-)-PENTALENIC ACID | - |
dc.subject.keywordPlus | RADICAL CYCLIZATION | - |
dc.subject.keywordPlus | ORGANIC-SYNTHESIS | - |
dc.subject.keywordPlus | NATURAL-PRODUCTS | - |
dc.subject.keywordPlus | IDEAL SYNTHESIS | - |
dc.subject.keywordPlus | PENTALENENE | - |
dc.subject.keywordPlus | CYCLOADDITION | - |
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