DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Jae-Hyuk | ko |
dc.contributor.author | Kim, Tae-Kyu | ko |
dc.contributor.author | Kim, Joong-Han | ko |
dc.contributor.author | Kong, Qingyu | ko |
dc.contributor.author | Cammarata, Marco | ko |
dc.contributor.author | Lorenc, Maciej | ko |
dc.contributor.author | Wulff, Michael | ko |
dc.contributor.author | Ihee, Hyot-Cherl | ko |
dc.date.accessioned | 2019-03-08T09:00:47Z | - |
dc.date.available | 2019-03-08T09:00:47Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2008-05 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.130, no.18, pp.5834 - 5834 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/251085 | - |
dc.description.abstract | This Communication reports simultaneous tracking of structural and kinetic information for the photoinduced elimination reaction of 1,2-diiodotetrafluoroethane in solution by transient X-ray diffraction. The transient structure of center dot CF2CF2I is determined to be a classical mixture whereas center dot CH2CH2I is bridged. Compared with the gas phase reaction, the secondary dissociation of center dot CF2CF2I into C2F4 and I is slowed down by a factor of 6 in solution. Transient X-ray diffraction offers a complementary method for capturing transient structures in solution which might be invisible or "optically silent" in time-resolved optical spectroscopy. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Capturing transient structures in the elimination reaction of haloalkane in solution by transient X-ray diffraction | - |
dc.type | Article | - |
dc.identifier.wosid | 000255629400002 | - |
dc.identifier.scopusid | 2-s2.0-42949135935 | - |
dc.type.rims | ART | - |
dc.citation.volume | 130 | - |
dc.citation.issue | 18 | - |
dc.citation.beginningpage | 5834 | - |
dc.citation.endingpage | 5834 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja710267u | - |
dc.contributor.localauthor | Kim, Tae-Kyu | - |
dc.contributor.localauthor | Ihee, Hyot-Cherl | - |
dc.contributor.nonIdAuthor | Kim, Joong-Han | - |
dc.contributor.nonIdAuthor | Kong, Qingyu | - |
dc.contributor.nonIdAuthor | Cammarata, Marco | - |
dc.contributor.nonIdAuthor | Lorenc, Maciej | - |
dc.contributor.nonIdAuthor | Wulff, Michael | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURES | - |
dc.subject.keywordPlus | AB-INITIO | - |
dc.subject.keywordPlus | RADICALS | - |
dc.subject.keywordPlus | DYNAMICS | - |
dc.subject.keywordPlus | PHOTODISSOCIATION | - |
dc.subject.keywordPlus | BR | - |
dc.subject.keywordPlus | CL | - |
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