DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Kyung-Hwan | ko |
dc.contributor.author | Ok, Tae-Dong | ko |
dc.contributor.author | Lee, Kwang-Yeol | ko |
dc.contributor.author | Lee, Hee-Seung | ko |
dc.contributor.author | Chang, Kyu-Tae | ko |
dc.contributor.author | Ihee, Hyot-Cherl | ko |
dc.contributor.author | Sohn, Jeong-Hun | ko |
dc.date.accessioned | 2019-03-08T07:35:02Z | - |
dc.date.available | 2019-03-08T07:35:02Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2010-09 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.34, pp.12027 - 12033 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/251064 | - |
dc.description.abstract | Herein we present the long-sought quantitative catalyst-substrate association relationships based on experimentally measured quantitative association preferences of diverse metathesis Mo and Ru catalysts (Mo-1, Schrock Mo; Mo-2, Schrock-Hoveyda Mo; Ru-1, Grubbs first generation Ru; Ru-2, Grubbs second generation Ru; Ru-3:, Grubbs-Hoveyda first generation Ru; and Ru-4, Grubbs-Hoveyda second generation Ru) to their substrates (alkenes, alkynes and allenes), determined directly by a general method based on FRET principle. The determined substrate preferences are proved to be dependent on the molecular identity of the catalyst, exhibiting the preference order of alkyne > alkene > allene for Mo-1 and Mo-2, allene > alkene > alkyne for Ru-1 and Ru-3, and alkyne > allene > alkene for Ru-2 and Ru-4. The results enable us to probe metathesis mechanisms by answering issues in metathesis reactions including the controversial reaction initiation in enyne or allenyne metathesis. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | RING-CLOSING METATHESIS | - |
dc.subject | IMIDO ALKYLIDENE COMPLEXES | - |
dc.subject | NOBEL LECTURE 2005 | - |
dc.subject | ENYNE METATHESIS | - |
dc.subject | OLEFIN-METATHESIS | - |
dc.subject | GRUBBS RUTHENIUM | - |
dc.subject | CROSS-METATHESIS | - |
dc.subject | METAL | - |
dc.subject | MECHANISM | - |
dc.subject | POLYMERIZATION | - |
dc.title | Quantitative Catalyst-Substrate Association Relationships between Metathesis Molybdenum or Ruthenium Carbene Complexes and Their Substrates | - |
dc.type | Article | - |
dc.identifier.wosid | 000281296700050 | - |
dc.identifier.scopusid | 2-s2.0-77956066502 | - |
dc.type.rims | ART | - |
dc.citation.volume | 132 | - |
dc.citation.issue | 34 | - |
dc.citation.beginningpage | 12027 | - |
dc.citation.endingpage | 12033 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja104193s | - |
dc.contributor.localauthor | Lee, Hee-Seung | - |
dc.contributor.localauthor | Ihee, Hyot-Cherl | - |
dc.contributor.nonIdAuthor | Lee, Kwang-Yeol | - |
dc.contributor.nonIdAuthor | Chang, Kyu-Tae | - |
dc.contributor.nonIdAuthor | Sohn, Jeong-Hun | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | RING-CLOSING METATHESIS | - |
dc.subject.keywordPlus | IMIDO ALKYLIDENE COMPLEXES | - |
dc.subject.keywordPlus | NOBEL LECTURE 2005 | - |
dc.subject.keywordPlus | ENYNE METATHESIS | - |
dc.subject.keywordPlus | OLEFIN-METATHESIS | - |
dc.subject.keywordPlus | GRUBBS RUTHENIUM | - |
dc.subject.keywordPlus | CROSS-METATHESIS | - |
dc.subject.keywordPlus | METAL | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
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