DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Jae Hyuk | ko |
dc.contributor.author | Wulff, Michael | ko |
dc.contributor.author | Bratos, Savo | ko |
dc.contributor.author | Petersen, Jakob | ko |
dc.contributor.author | Guerin, Laurent | ko |
dc.contributor.author | Leicknam, Jean-Claude | ko |
dc.contributor.author | Carnmarata, Marco | ko |
dc.contributor.author | Kong, Qingyu | ko |
dc.contributor.author | Kim, Jeongho | ko |
dc.contributor.author | Moller, Klaus B. | ko |
dc.contributor.author | Ihee, Hyotcherl | ko |
dc.date.accessioned | 2019-03-07T09:30:28Z | - |
dc.date.available | 2019-03-07T09:30:28Z | - |
dc.date.created | 2013-04-09 | - |
dc.date.issued | 2013-02 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.135, no.8, pp.3255 - 3261 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/250871 | - |
dc.description.abstract | Molecules are often born with high energy and large-amplitude vibrations. In solution, a newly formed molecule cools down by transferring energy to the surrounding solvent molecules. The progression of the molecular and solute-solvent cage structure during this fundamental process has been elusive, and spectroscopic data generally do not provide such structural information. Here, we use picosecond X-ray liquidography (solution scattering) to visualize time-dependent structural changes associated with the vibrational relaxation of I-2 molecules in two different solvents, CCl4 and cyclohexane. The birth and vibrational relaxation of I-2 molecules and the associated rearrangement of solvent molecules are mapped out in the form of a temporally varying interatomic distance distribution. The I-I distance increases up to similar to 4 angstrom and returns to the equilibrium distance (2.67 angstrom) in the ground state, and the first solvation cage expands by similar to 1.5 angstrom along the I-I axis and then shrinks back accompanying the structural change of the I-2 molecule. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | X-RAY-DIFFRACTION | - |
dc.subject | PROTEIN STRUCTURAL DYNAMICS | - |
dc.subject | SOLUTION SCATTERING REVEALS | - |
dc.subject | GEMINATE RECOMBINATION | - |
dc.subject | SOLVATION DYNAMICS | - |
dc.subject | REACTION PATHWAYS | - |
dc.subject | CONDENSED-PHASE | - |
dc.subject | IODINE | - |
dc.subject | PROBE | - |
dc.subject | PICOSECOND | - |
dc.title | Filming the Birth of Molecules and Accompanying Solvent Rearrangement | - |
dc.type | Article | - |
dc.identifier.wosid | 000315618900061 | - |
dc.identifier.scopusid | 2-s2.0-84874630190 | - |
dc.type.rims | ART | - |
dc.citation.volume | 135 | - |
dc.citation.issue | 8 | - |
dc.citation.beginningpage | 3255 | - |
dc.citation.endingpage | 3261 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja312513w | - |
dc.contributor.localauthor | Ihee, Hyotcherl | - |
dc.contributor.nonIdAuthor | Lee, Jae Hyuk | - |
dc.contributor.nonIdAuthor | Wulff, Michael | - |
dc.contributor.nonIdAuthor | Bratos, Savo | - |
dc.contributor.nonIdAuthor | Petersen, Jakob | - |
dc.contributor.nonIdAuthor | Guerin, Laurent | - |
dc.contributor.nonIdAuthor | Leicknam, Jean-Claude | - |
dc.contributor.nonIdAuthor | Carnmarata, Marco | - |
dc.contributor.nonIdAuthor | Kong, Qingyu | - |
dc.contributor.nonIdAuthor | Kim, Jeongho | - |
dc.contributor.nonIdAuthor | Moller, Klaus B. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | X-RAY-DIFFRACTION | - |
dc.subject.keywordPlus | PROTEIN STRUCTURAL DYNAMICS | - |
dc.subject.keywordPlus | SOLUTION SCATTERING REVEALS | - |
dc.subject.keywordPlus | GEMINATE RECOMBINATION | - |
dc.subject.keywordPlus | SOLVATION DYNAMICS | - |
dc.subject.keywordPlus | REACTION PATHWAYS | - |
dc.subject.keywordPlus | CONDENSED-PHASE | - |
dc.subject.keywordPlus | IODINE | - |
dc.subject.keywordPlus | PROBE | - |
dc.subject.keywordPlus | PICOSECOND | - |
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