Preparation, characterization, and reactivity of Pt/SDBC catalysts for the hydrogen-water isotopic exchange reaction

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Pt/SDBC catalysts, which are used for the hydrogen-water isotopic exchange reaction, were prepared. TGA experiments showed that the treatment temperature of Pt/SDBC catalysts in inert gas is limited to 400 degrees C and the maximum allowable heat treatment temperature in oxygen is 200 degrees C. From nitrogen adsorption and hydrogen chemisorption measurements, it was:shown that the dispersion of platinum particles depended on the physical properties, i.e., specific surface area and pore structure of SDBC. It was found that the heat treatment could not impact the structure of SDBC and the oxygen treatment at 150 degrees C improved the platinum dispersion. It was shown by XPS analysis that the oxygen treatment of impregnated Pt/SDBC increased the fraction of platinum metal state and platinum dispersion. As the supported platinum area increases, the catalytic activity of Pt/SDBC for the hydrogen-water vapor isotopic exchange reaction increases. It indicates that the hydrogen chemisorption measurement can be used to estimate the catalytic activities of Pt/SDBC catalysts. It was not observed that the particle size of supported platinum affected the specific reaction rate at 60 degrees C. It implies that this reaction is structure insensitive.
Publisher
ELSEVIER SCIENCE SA
Issue Date
1999-12
Language
English
Article Type
Article
Keywords

PLATINUM; DEUTERIUM; VAPOR

Citation

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, v.242, no.3, pp.709 - 715

ISSN
0236-5731
URI
http://hdl.handle.net/10203/250684
Appears in Collection
CBE-Journal Papers(저널논문)
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