DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kang, Dahye | ko |
dc.contributor.author | Kim, Taehwan | ko |
dc.contributor.author | Lee, Hyunpyo | ko |
dc.contributor.author | Hong, Sungwoo | ko |
dc.date.accessioned | 2019-01-22T08:31:09Z | - |
dc.date.available | 2019-01-22T08:31:09Z | - |
dc.date.created | 2018-12-26 | - |
dc.date.created | 2018-12-26 | - |
dc.date.issued | 2018-12 | - |
dc.identifier.citation | ORGANIC LETTERS, v.20, no.23, pp.7571 - 7575 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/10203/249008 | - |
dc.description.abstract | Catalytic ring-opening phosphonation and phosphatation of vinyl aziridines have been developed in a regiodivergent fashion, giving linear and branched products. Generation of P-centered radicals enables S(N)2'-type ring-opening reactions of vinyl aziridines to afford delta-amino alkylphosphorus products at room temperature. On the other hand, in situ generated phosphate anions via the Ag-catalyzed aerobic oxidation of phosphonyl reactants underwent S(N)2 reaction to provide branched phosphorus-containing amine products. Furthermore, this divergent methodology serves as a powerful tool for the stereospecific synthesis of phosphorus-containing amino acid derivatives. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Regiodivergent Ring-Opening Cross-Coupling of Vinyl Aziridines with Phosphorus Nucleophiles: Access to Phosphorus-Containing Amino Acid Derivatives | - |
dc.type | Article | - |
dc.identifier.wosid | 000452930100049 | - |
dc.identifier.scopusid | 2-s2.0-85056506527 | - |
dc.type.rims | ART | - |
dc.citation.volume | 20 | - |
dc.citation.issue | 23 | - |
dc.citation.beginningpage | 7571 | - |
dc.citation.endingpage | 7575 | - |
dc.citation.publicationname | ORGANIC LETTERS | - |
dc.identifier.doi | 10.1021/acs.orglett.8b03309 | - |
dc.contributor.localauthor | Hong, Sungwoo | - |
dc.contributor.nonIdAuthor | Lee, Hyunpyo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | ASYMMETRIC-SYNTHESIS | - |
dc.subject.keywordPlus | NITROGEN-HETEROCYCLES | - |
dc.subject.keywordPlus | CYCLIZATION | - |
dc.subject.keywordPlus | PHOSPHORYLATION | - |
dc.subject.keywordPlus | CYCLOADDITIONS | - |
dc.subject.keywordPlus | PHOSPHONATION | - |
dc.subject.keywordPlus | BIOSYNTHESIS | - |
dc.subject.keywordPlus | CATALYST | - |
dc.subject.keywordPlus | LIGANDS | - |
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