DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gupta, G | ko |
dc.contributor.author | Slanac, DA | ko |
dc.contributor.author | Kumar, P | ko |
dc.contributor.author | Wiggins-Camacho, JD | ko |
dc.contributor.author | Kim, Jeongnam | ko |
dc.contributor.author | Ryoo, Ryong | ko |
dc.contributor.author | Stevenson, KJ | ko |
dc.contributor.author | Johnston, KP | ko |
dc.date.accessioned | 2011-07-25T02:46:08Z | - |
dc.date.available | 2011-07-25T02:46:08Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2010-06 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY C, v.114, no.24, pp.10796 - 10805 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.uri | http://hdl.handle.net/10203/24696 | - |
dc.description.abstract | In this manuscript, we have synthesized a stable fuel cell catalyst composed of presynthesized Pt nanocrystals (<4 nm) on graphitic mesoporous carbon. The catalyst shows negligible loss in mass activity and active surface area after an accelerated durability test (1000 cycles, 0.5-1.2 V), whereas the commercial Pt on amorphous carbon loses similar to 70% in activity and area. Strong Pt graphite interactions, resulting from metal/support orbital overlap (pi-backbonding) coupled with partial charge transfer, as shown by XPS, and a low coverage of weakly bound ligands on the Pt surface facilitated high dispersion and loadings up to 20 wt %. The high oxidation resistance of the graphitized carbon, along with the strong Pt-C interactions, helped to maintain electrical contact between the metal and carbon while mitigating Pt dissolution, ripening, and coalescence. The ability to disperse well-defined metal nanoparticles onto graphitic mesoporous carbon offers the potential for creating highly stable and active catalysts. | - |
dc.description.sponsorship | This material is based upon work supported in part by the STC Program of the National Science Foundation under Agreement No. CHE-9876674, the Robert A. Welch Foundation (Grants F-1319 and F-1529), and the National Science Foundation (CHE-0809770 and CHE-0618242). R.R. acknowledges support from the Ministry of Education, Science and Technology in Korea through the National Honor Scientist Program. | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | MEMBRANE FUEL-CELLS | - |
dc.subject | PT/C CATALYTIC CATHODE | - |
dc.subject | PLATINUM NANOPARTICLES | - |
dc.subject | DURABILITY ENHANCEMENT | - |
dc.subject | SURFACE MODIFICATION | - |
dc.subject | SUPPORT MATERIAL | - |
dc.subject | SILICA | - |
dc.subject | NANOCRYSTALS | - |
dc.subject | PERFORMANCE | - |
dc.subject | NANOTUBES | - |
dc.title | Highly Stable Pt/Ordered Graphitic Mesoporous Carbon Electrocatalysts for Oxygen Reduction | - |
dc.type | Article | - |
dc.identifier.wosid | 000278845300020 | - |
dc.identifier.scopusid | 2-s2.0-77953754789 | - |
dc.type.rims | ART | - |
dc.citation.volume | 114 | - |
dc.citation.issue | 24 | - |
dc.citation.beginningpage | 10796 | - |
dc.citation.endingpage | 10805 | - |
dc.citation.publicationname | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.identifier.doi | 10.1021/jp907015j | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Ryoo, Ryong | - |
dc.contributor.nonIdAuthor | Gupta, G | - |
dc.contributor.nonIdAuthor | Slanac, DA | - |
dc.contributor.nonIdAuthor | Kumar, P | - |
dc.contributor.nonIdAuthor | Wiggins-Camacho, JD | - |
dc.contributor.nonIdAuthor | Stevenson, KJ | - |
dc.contributor.nonIdAuthor | Johnston, KP | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | MEMBRANE FUEL-CELLS | - |
dc.subject.keywordPlus | PT/C CATALYTIC CATHODE | - |
dc.subject.keywordPlus | PLATINUM NANOPARTICLES | - |
dc.subject.keywordPlus | DURABILITY ENHANCEMENT | - |
dc.subject.keywordPlus | SURFACE MODIFICATION | - |
dc.subject.keywordPlus | SUPPORT MATERIAL | - |
dc.subject.keywordPlus | SILICA | - |
dc.subject.keywordPlus | NANOCRYSTALS | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | NANOTUBES | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.