DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Miji | ko |
dc.contributor.author | Shin, TaeIl | ko |
dc.contributor.author | Lee, Ansoo | ko |
dc.contributor.author | Kim, Hyunwoo | ko |
dc.date.accessioned | 2018-11-12T04:53:31Z | - |
dc.date.available | 2018-11-12T04:53:31Z | - |
dc.date.created | 2018-10-22 | - |
dc.date.created | 2018-10-22 | - |
dc.date.created | 2018-10-22 | - |
dc.date.issued | 2018-09 | - |
dc.identifier.citation | ORGANOMETALLICS, v.37, no.19, pp.3253 - 3258 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10203/246588 | - |
dc.description.abstract | A synergistic ligand effect between NHC and phosphorus ligands in Pd-catalyzed Buchwald-Hartwig amination reactions was demonstrated with tunable pi-acceptor bicyclic bridgehead phosphoramidite (briphos) ligands. The catalytic activity of NHC-Pd-L (L = phosphorus ligand) precatalysts depends on the electronic properties of L. A NHC-Pd-L catalyst with an N-cyclohexyl-substituted briphos ligand was found to be highly efficient. A series of C-N bond coupling reactions between primary or secondary amines and aryl chlorides were performed with high yields under mild reaction conditions. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Synergistic Ligand Effect between N-Heterocyclic Carbene (NHC) and Bicyclic Phosphoramidite (Briphos) Ligands in Pd-Catalyzed Amination | - |
dc.type | Article | - |
dc.identifier.wosid | 000447118700006 | - |
dc.identifier.scopusid | 2-s2.0-85053926841 | - |
dc.type.rims | ART | - |
dc.citation.volume | 37 | - |
dc.citation.issue | 19 | - |
dc.citation.beginningpage | 3253 | - |
dc.citation.endingpage | 3258 | - |
dc.citation.publicationname | ORGANOMETALLICS | - |
dc.identifier.doi | 10.1021/acs.organomet.8b00413 | - |
dc.contributor.localauthor | Kim, Hyunwoo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | CROSS-COUPLING REACTIONS | - |
dc.subject.keywordPlus | ORGANOMETALLIC CHEMISTRY | - |
dc.subject.keywordPlus | PALLADIUM COMPLEXES | - |
dc.subject.keywordPlus | ARYL CHLORIDES | - |
dc.subject.keywordPlus | DESIGNING PD | - |
dc.subject.keywordPlus | PI-ACCEPTOR | - |
dc.subject.keywordPlus | C-N | - |
dc.subject.keywordPlus | PRECATALYST | - |
dc.subject.keywordPlus | ARYLATION | - |
dc.subject.keywordPlus | ALCOHOLS | - |
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