DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hwang, Yeongyu | ko |
dc.contributor.author | PARK, YOONSU | ko |
dc.contributor.author | Kim, Yeong Bum | ko |
dc.contributor.author | Kim, Dongwook | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2018-11-12T04:18:52Z | - |
dc.date.available | 2018-11-12T04:18:52Z | - |
dc.date.created | 2018-10-22 | - |
dc.date.created | 2018-10-22 | - |
dc.date.created | 2018-10-22 | - |
dc.date.created | 2018-10-22 | - |
dc.date.issued | 2018-10 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.41, pp.13565 - 13569 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/246321 | - |
dc.description.abstract | Two mechanistic pathways, that is, electrocyclization and electrophilic aromatic substitution, are operative in most intramolecular C-H amination reactions proceeding by metal nitrenoid catalysis. Reported here is an alternative mechanistic scaffold leading to benzofused delta-lactams selectively. Integrated experimental and computational analysis revealed that the reaction proceeds by a key spirocyclization step followed by a skeletal rearrangement. Based on this mechanistic insight, a new synthetic route to spirolactams has been developed. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Revisiting Arene C(sp(2))-H Amidation by Intramolecular Transfer of Iridium Nitrenoids: Evidence for a Spirocyclization Pathway | - |
dc.type | Article | - |
dc.identifier.wosid | 000446306600034 | - |
dc.identifier.scopusid | 2-s2.0-85053629948 | - |
dc.type.rims | ART | - |
dc.citation.volume | 57 | - |
dc.citation.issue | 41 | - |
dc.citation.beginningpage | 13565 | - |
dc.citation.endingpage | 13569 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.201808892 | - |
dc.contributor.localauthor | PARK, YOONSU | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | C-H amidation | - |
dc.subject.keywordAuthor | iridium | - |
dc.subject.keywordAuthor | reaction mechanisms | - |
dc.subject.keywordAuthor | rearrangements | - |
dc.subject.keywordAuthor | spirocompounds | - |
dc.subject.keywordPlus | C-H AMINATION | - |
dc.subject.keywordPlus | DIENONE-PHENOL REARRANGEMENT | - |
dc.subject.keywordPlus | N-ACYLNITRENIUM IONS | - |
dc.subject.keywordPlus | BOND ACTIVATION | - |
dc.subject.keywordPlus | CATALYZED SYNTHESIS | - |
dc.subject.keywordPlus | ARYL AZIDES | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | INDOLES | - |
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