DC Field | Value | Language |
---|---|---|
dc.contributor.author | Mullane, Kimberly C. | ko |
dc.contributor.author | Ryu, Ho | ko |
dc.contributor.author | Cheisson, Thibault | ko |
dc.contributor.author | Grant, Lauren N. | ko |
dc.contributor.author | Park, Ji Young | ko |
dc.contributor.author | Manor, Brian C. | ko |
dc.contributor.author | Carroll, Patrick J. | ko |
dc.contributor.author | Baik, Mu-Hyun | ko |
dc.contributor.author | Mindiola, Daniel J. | ko |
dc.contributor.author | Schelter, Eric J. | ko |
dc.date.accessioned | 2018-10-19T00:49:24Z | - |
dc.date.available | 2018-10-19T00:49:24Z | - |
dc.date.created | 2018-10-08 | - |
dc.date.created | 2018-10-08 | - |
dc.date.issued | 2018-09 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.140, no.36, pp.11335 - 11340 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/246161 | - |
dc.description.abstract | Uranium complexes in the +3 and +4 oxidation states were prepared using the anionic PN- (PN- = (N-(2-(diisopropylphosphino) -4-methylphenyl)-2,4,6-trimethylanilide) ligand framework. New complexes include the halide starting materials, (PN)(2)(UI)-I-III (1) and (PN)(2)(UCl2)-Cl-IV (2), which both yield (PN)(2)U-IV(N-3)(2) (3) by reaction with NaN3. Compound 3 was reduced with potassium graphite to produce a putative, transient uranium-nitrido moiety that underwent an intramolecular C-H activation to form a rare example of a parent imido complex, [K(THF)(3)][(PN)U-IV(= NH)[(Pr2P)-Pr-i(C6H3Me)N(C6H2Me2CH2)]] (4). Calculated reaction energy profiles strongly suggest that a C-H insertion becomes unfavorable when a reductant is present, offering a distinctively different reaction pathway than previously observed for other uranium nitride complexes. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | MOLECULAR-STRUCTURE | - |
dc.subject | TITANIUM NITRIDES | - |
dc.subject | NITROGEN-FIXATION | - |
dc.subject | SCHROCK CYCLE | - |
dc.subject | CHEMISTRY | - |
dc.subject | CRYSTAL | - |
dc.subject | MONONUCLEAR | - |
dc.subject | DINITROGEN | - |
dc.subject | REDUCTION | - |
dc.subject | RELEVANT | - |
dc.title | C-H Bond Addition across a Transient Uranium-Nitrido Moiety and Formation of a Parent Uranium Imido Complex | - |
dc.type | Article | - |
dc.identifier.wosid | 000444793400032 | - |
dc.identifier.scopusid | 2-s2.0-85050882995 | - |
dc.type.rims | ART | - |
dc.citation.volume | 140 | - |
dc.citation.issue | 36 | - |
dc.citation.beginningpage | 11335 | - |
dc.citation.endingpage | 11340 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/jacs.8b06090 | - |
dc.contributor.localauthor | Baik, Mu-Hyun | - |
dc.contributor.nonIdAuthor | Mullane, Kimberly C. | - |
dc.contributor.nonIdAuthor | Cheisson, Thibault | - |
dc.contributor.nonIdAuthor | Grant, Lauren N. | - |
dc.contributor.nonIdAuthor | Park, Ji Young | - |
dc.contributor.nonIdAuthor | Manor, Brian C. | - |
dc.contributor.nonIdAuthor | Carroll, Patrick J. | - |
dc.contributor.nonIdAuthor | Mindiola, Daniel J. | - |
dc.contributor.nonIdAuthor | Schelter, Eric J. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | TITANIUM NITRIDES | - |
dc.subject.keywordPlus | NITROGEN-FIXATION | - |
dc.subject.keywordPlus | SCHROCK CYCLE | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | CRYSTAL | - |
dc.subject.keywordPlus | MONONUCLEAR | - |
dc.subject.keywordPlus | DINITROGEN | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | RELEVANT | - |
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