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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Piers' borane- mediated hydrosilylation of epoxides and cyclic ethers

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dc.contributor.authorZhang, Jianboko
dc.contributor.authorPark, Sehoonko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2018-08-20T07:48:39Z-
dc.date.available2018-08-20T07:48:39Z-
dc.date.created2018-08-06-
dc.date.created2018-08-06-
dc.date.issued2018-07-
dc.identifier.citationCHEMICAL COMMUNICATIONS, v.54, no.52, pp.7243 - 7246-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/244845-
dc.description.abstractWe report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers' borane (C6F5)(2)BH with hydrosilanes in the presence of an epoxide revealed that an alkyloxy(diaryl)borane (C6F5)(2)BOR is readily formed as a catalytically competent species for the outer-sphere hydrosilylation of epoxides and cyclic ethers.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectCATALYTIC HYDROGENOLYSIS-
dc.subjectSI-H-
dc.subjectREDUCTION-
dc.subjectMECHANISM-
dc.subjectALCOHOLS-
dc.subjectBORON-
dc.subjectPOLYMERIZATION-
dc.subjectDEOXYGENATION-
dc.subjectHYDROBORATION-
dc.subjectREARRANGEMENT-
dc.titlePiers' borane- mediated hydrosilylation of epoxides and cyclic ethers-
dc.typeArticle-
dc.identifier.wosid000436290100032-
dc.identifier.scopusid2-s2.0-85049195024-
dc.type.rimsART-
dc.citation.volume54-
dc.citation.issue52-
dc.citation.beginningpage7243-
dc.citation.endingpage7246-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/c8cc03741h-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorZhang, Jianbo-
dc.contributor.nonIdAuthorPark, Sehoon-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCATALYTIC HYDROGENOLYSIS-
dc.subject.keywordPlusSI-H-
dc.subject.keywordPlusREDUCTION-
dc.subject.keywordPlusMECHANISM-
dc.subject.keywordPlusALCOHOLS-
dc.subject.keywordPlusBORON-
dc.subject.keywordPlusPOLYMERIZATION-
dc.subject.keywordPlusDEOXYGENATION-
dc.subject.keywordPlusHYDROBORATION-
dc.subject.keywordPlusREARRANGEMENT-
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CH-Journal Papers(저널논문)
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