DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gunasekar, Gunniya Hariyanandam | ko |
dc.contributor.author | Shin, Jeongcheol | ko |
dc.contributor.author | Jung, Kwang-Deog | ko |
dc.contributor.author | Park, Kiyoung | ko |
dc.contributor.author | Yoon, Sungho | ko |
dc.date.accessioned | 2018-07-24T02:25:03Z | - |
dc.date.available | 2018-07-24T02:25:03Z | - |
dc.date.created | 2018-07-04 | - |
dc.date.created | 2018-07-04 | - |
dc.date.issued | 2018-05 | - |
dc.identifier.citation | ACS CATALYSIS, v.8, no.5, pp.4346 - 4353 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.uri | http://hdl.handle.net/10203/244061 | - |
dc.description.abstract | One bottleneck in the realization of CO2 conversion into value-added compounds is the lack of catalysts with both excellent activity and recyclability. Herein, a catalyst is designed for the hydrogenation of CO2 to formate to boost up these features by considering the leaching pathway of previously reported heterogenized catalyst; the design strategy incorporates oxyanionic ligand(s) in the coordination sphere to provide a pathway for both preventing the deleterious interactions and assisting the heterolysis of H-2. The tailored heterogenized catalyst, [bpy-CTF-Ru(acac)(2)]Cl, demonstrated excellent recyclability over consecutive runs with a highest turnover frequency of 22 700 h(-1), and produced a highest formate concentration of 1.8 M in 3 h. This work is significant in elucidating new principles for the development of industrially viable hydrogenation catalysts. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Design Strategy toward Recyclable and Highly Efficient Heterogeneous Catalysts for the Hydrogenation of CO2 to Formate | - |
dc.type | Article | - |
dc.identifier.wosid | 000431727300067 | - |
dc.identifier.scopusid | 2-s2.0-85046632295 | - |
dc.type.rims | ART | - |
dc.citation.volume | 8 | - |
dc.citation.issue | 5 | - |
dc.citation.beginningpage | 4346 | - |
dc.citation.endingpage | 4353 | - |
dc.citation.publicationname | ACS CATALYSIS | - |
dc.identifier.doi | 10.1021/acscatal.8b00392 | - |
dc.contributor.localauthor | Park, Kiyoung | - |
dc.contributor.nonIdAuthor | Gunasekar, Gunniya Hariyanandam | - |
dc.contributor.nonIdAuthor | Jung, Kwang-Deog | - |
dc.contributor.nonIdAuthor | Yoon, Sungho | - |
dc.description.isOpenAccess | Y | - |
dc.type.journalArticle | Article | - |
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