DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Seung-Chul | ko |
dc.contributor.author | Kang, Bong Joo | ko |
dc.contributor.author | Lee, Ji-Ah | ko |
dc.contributor.author | Lee, Seung-Heon | ko |
dc.contributor.author | Jazbinsek, Mojca | ko |
dc.contributor.author | Yoon, Woojin | ko |
dc.contributor.author | Yun, Hoseop | ko |
dc.contributor.author | Rotermund, Fabian | ko |
dc.contributor.author | Kwon, O-Pil | ko |
dc.date.accessioned | 2018-06-16T07:37:15Z | - |
dc.date.available | 2018-06-16T07:37:15Z | - |
dc.date.created | 2018-06-11 | - |
dc.date.created | 2018-06-11 | - |
dc.date.created | 2018-06-11 | - |
dc.date.created | 2018-06-11 | - |
dc.date.issued | 2018-05 | - |
dc.identifier.citation | ADVANCED OPTICAL MATERIALS, v.6, no.10, pp.1701258 | - |
dc.identifier.issn | 2195-1071 | - |
dc.identifier.uri | http://hdl.handle.net/10203/242539 | - |
dc.description.abstract | New molecular salt crystals based on linear-shaped polymer-like cation–anion assembly exhibiting extremely large nonlinear optical response and high THz generation efficiency are reported. Two hydroxy benzothialzolium PMB (2-(4-(4-(hydroxymethyl)piperidin-1-yl)styryl)-3-methylbenzo[d]thiazol-3-ium) crystals with different benzenesulfonate counter anions provide isomorphic crystal structure with acentric monoclinic Cc space group symmetry. In contrast to previously reported benchmark nonlinear optical salt crystals with a parallel-type cation–anion assembly, newly developed PMB-based crystals exhibit a series-type cation–anion assembly mediated by strong bidentate-like hydrogen-bonds. Such series-type cation–anion assembly results in perfect alignment of highly nonlinear PMB cations in the crystalline state, leading to extremely large diagonal component of the second-order nonlinear optical coefficient exceeding that of the state-of-the-art nonlinear optical crystals. In THz wave generation experiments based on optical rectification, a 0.33 mm thick PMB crystal generates intense THz pulses with peak-to-peak THz electric field of 430 kV cm | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Single Crystals Based on Hydrogen-Bonding Mediated Cation–Anion Assembly with Extremely Large Optical Nonlinearity and Their Application for Intense THz Wave Generation | - |
dc.type | Article | - |
dc.identifier.wosid | 000434035600004 | - |
dc.identifier.scopusid | 2-s2.0-85044239551 | - |
dc.type.rims | ART | - |
dc.citation.volume | 6 | - |
dc.citation.issue | 10 | - |
dc.citation.beginningpage | 1701258 | - |
dc.citation.publicationname | ADVANCED OPTICAL MATERIALS | - |
dc.identifier.doi | 10.1002/adom.201701258 | - |
dc.contributor.localauthor | Rotermund, Fabian | - |
dc.contributor.nonIdAuthor | Lee, Seung-Chul | - |
dc.contributor.nonIdAuthor | Kang, Bong Joo | - |
dc.contributor.nonIdAuthor | Lee, Ji-Ah | - |
dc.contributor.nonIdAuthor | Lee, Seung-Heon | - |
dc.contributor.nonIdAuthor | Jazbinsek, Mojca | - |
dc.contributor.nonIdAuthor | Yoon, Woojin | - |
dc.contributor.nonIdAuthor | Yun, Hoseop | - |
dc.contributor.nonIdAuthor | Kwon, O-Pil | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | nonlinear optics | - |
dc.subject.keywordAuthor | organic crystals | - |
dc.subject.keywordAuthor | terahertz waves | - |
dc.subject.keywordPlus | STILBAZOLIUM DERIVATIVES | - |
dc.subject.keywordPlus | TERAHERTZ APPLICATIONS | - |
dc.subject.keywordPlus | MOLECULAR-CRYSTALS | - |
dc.subject.keywordPlus | ORGANIC SALTS | - |
dc.subject.keywordPlus | RECTIFICATION | - |
dc.subject.keywordPlus | TOSYLATE | - |
dc.subject.keywordPlus | FREQUENCY | - |
dc.subject.keywordPlus | PULSES | - |
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