DC Field | Value | Language |
---|---|---|
dc.contributor.author | Choi, Hanseul | ko |
dc.contributor.author | Carboni, Michele | ko |
dc.contributor.author | Kim, You Kyung | ko |
dc.contributor.author | Jung, Chan Ho | ko |
dc.contributor.author | Moon, Song Yi | ko |
dc.contributor.author | Koebel, Matthias M. | ko |
dc.contributor.author | Park, Jeong Young | ko |
dc.date.accessioned | 2018-05-24T02:23:19Z | - |
dc.date.available | 2018-05-24T02:23:19Z | - |
dc.date.created | 2018-05-08 | - |
dc.date.created | 2018-05-08 | - |
dc.date.issued | 2018-05 | - |
dc.identifier.citation | CATALYSIS LETTERS, v.148, no.5, pp.1504 - 1513 | - |
dc.identifier.issn | 1011-372X | - |
dc.identifier.uri | http://hdl.handle.net/10203/242235 | - |
dc.description.abstract | We demonstrate the preparation and catalytic testing of nanocatalysts composed of TiO2 synthesized in aerogel using a supercritical drying process with Pt nanoparticles deposited on the mesopore oxide surface. By controlling the aging time, we found conditions that led to TiO2 with a surface area among the highest ever reported for a TiO2 material in aerogel form (similar to 685 m(2) g(- 1)). The chosen synthesis route also features good control over the pore volume and pore size. Even though our aerogel TiO2 support showed an amorphous structure before calcination, 90.2% anatase and 9.8% rutile phases co-existed after calcination at 500 A degrees C for 2 h with an average particle size of about 17 nm based on XRD results. The as-synthesized TiO2 and Pt/TiO2 were both used as catalysts for the CO oxidation reaction. Uncalcined Pt/TiO2 showed 100% conversion at 300 A degrees C. After calcination, Pt/TiO2 exhibited a significantly higher catalytic activity, showing 100% conversion at 125 A degrees C and an activation energy of only 13.4 kcal mol(- 1). We show that TiO2 synthesized by the aerogel method can be an excellent support material for nanocatalysis because of its high surface area and facile and scalable synthesis. [GRAPHICS] . | - |
dc.language | English | - |
dc.publisher | SPRINGER | - |
dc.subject | SENSITIZED SOLAR-CELLS | - |
dc.subject | ANATASE TIO2 | - |
dc.subject | MESOPOROUS TIO2 | - |
dc.subject | PARTICLE-SIZE | - |
dc.subject | PHOTOCATALYTIC ACTIVITY | - |
dc.subject | STRUCTURAL-PROPERTIES | - |
dc.subject | PT/TIO2 CATALYSTS | - |
dc.subject | TITANIUM-DIOXIDE | - |
dc.subject | PLATINUM | - |
dc.subject | NANOCATALYSTS | - |
dc.title | Synthesis of High Surface Area TiO2 Aerogel Support with Pt Nanoparticle Catalyst and CO Oxidation Study | - |
dc.type | Article | - |
dc.identifier.wosid | 000430722800027 | - |
dc.identifier.scopusid | 2-s2.0-85044204593 | - |
dc.type.rims | ART | - |
dc.citation.volume | 148 | - |
dc.citation.issue | 5 | - |
dc.citation.beginningpage | 1504 | - |
dc.citation.endingpage | 1513 | - |
dc.citation.publicationname | CATALYSIS LETTERS | - |
dc.identifier.doi | 10.1007/s10562-018-2355-y | - |
dc.contributor.localauthor | Park, Jeong Young | - |
dc.contributor.nonIdAuthor | Carboni, Michele | - |
dc.contributor.nonIdAuthor | Kim, You Kyung | - |
dc.contributor.nonIdAuthor | Moon, Song Yi | - |
dc.contributor.nonIdAuthor | Koebel, Matthias M. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Aerogel | - |
dc.subject.keywordAuthor | TiO2 | - |
dc.subject.keywordAuthor | Pt nanoparticle | - |
dc.subject.keywordAuthor | Heterogeneous catalyst | - |
dc.subject.keywordAuthor | CO oxidation | - |
dc.subject.keywordPlus | SENSITIZED SOLAR-CELLS | - |
dc.subject.keywordPlus | ANATASE TIO2 | - |
dc.subject.keywordPlus | MESOPOROUS TIO2 | - |
dc.subject.keywordPlus | PARTICLE-SIZE | - |
dc.subject.keywordPlus | PHOTOCATALYTIC ACTIVITY | - |
dc.subject.keywordPlus | STRUCTURAL-PROPERTIES | - |
dc.subject.keywordPlus | PT/TIO2 CATALYSTS | - |
dc.subject.keywordPlus | TITANIUM-DIOXIDE | - |
dc.subject.keywordPlus | PLATINUM | - |
dc.subject.keywordPlus | NANOCATALYSTS | - |
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